Early transition metal (group 3–5, lanthanides and actinides) and main group metal (group 1, 2, and 13) catalyzed hydroamination

AL Reznichenko, KC Hultzsch - Hydrofunctionalization, 2013 - Springer
The hydroamination of alkenes, dienes, allenes, and alkynes by early transition metal
catalysts has seen significant progress over the last decade, especially with respect to …

Transition metal‐catalyzed asymmetric hydroamination of alkenes (AHA)

KC Hultzsch - Advanced Synthesis & Catalysis, 2005 - Wiley Online Library
The hydroamination of unsaturated carbon‐carbon linkages allows a facile and highly atom‐
economical access to industrially relevant nitrogen‐containing basic and fine chemicals as …

Hydroamination and hydroaminoalkylation of alkenes by group 3–5 elements: recent developments and comparison with late transition metals

J Hannedouche, E Schulz - Organometallics, 2018 - ACS Publications
This short review highlights recent catalyst developments from group 3–5 elements reported
in the past few years to promote two highly atom-saving transformations, namely …

Recent advances in metal free-and late transition metal-catalysed hydroamination of unactivated alkenes

E Bernoud, C Lepori, M Mellah, E Schulz… - Catalysis Science & …, 2015 - pubs.rsc.org
This Perspective article outlines some of the recent advancements completed in the
development of (chiral) metal-free and late-transition metal catalysts for the inter-and …

Isolation of catalytic intermediates in hydroamination reactions: insertion of internal alkynes into a zirconium–amido bond

DC Leitch, CS Turner, LL Schafer - … Chemie International Edition, 2010 - Wiley Online Library
Metal-catalyzed hydroamination, a direct and atom-economic approach for the formation of
CÀN bonds, is becoming an increasingly powerful method in organic synthesis.[1] This …

Catalytic asymmetric hydroamination of non-activated olefins

KC Hultzsch - Organic & Biomolecular Chemistry, 2005 - pubs.rsc.org
Hydroamination is a highly atom-economical process in which an amine N–H functionality is
added to an unsaturated carbon–carbon linkage. This potentially highly useful process gives …

Progression of hydroamination catalyzed by late transition-metal complexes from activated to unactivated alkenes

S Ma, JF Hartwig - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Catalytic intermolecular hydroamination of alkenes is an atom-and step-
economical method for the synthesis of amines, which have important applications as …

Recent metal-catalysed asymmetric hydroaminations of alkenes

C Michon, MA Abadie, F Medina… - Journal of …, 2017 - Elsevier
The selective and asymmetric addition of amines across alkene C= C bonds
(hydroamination of alkenes) is one of the most important tool to synthesise chiral amines …

Intramolecular enantioselective hydroamination catalyzed by rare earth binaphthylamides

J Hannedouche, J Collin, A Trifonov… - Journal of Organometallic …, 2011 - Elsevier
Asymmetric intramolecular hydroamination reaction is a stately way to prepare chiral
nitrogen-containing heterocyclic compounds. We report in this account our personal …

Modular N,O‐Chelating Ligands: Group‐4 Amidate Complexes for Catalytic Hydroamination

AV Lee, LL Schafer - European journal of inorganic chemistry, 2007 - Wiley Online Library
Amidate ligands have been used as a modular ligand set for early transition‐metal
complexes, and have been found to exhibit high reactivity in the catalytic hydroamination of …