A visible light-induced photocatalytic aerobic oxidation/semipinacol rearrangement has
been successfully developed. This methodology allows for efficient conversion of a wide …

Conspectus The monoterpene indole alkaloids, containing over 3000 known members and
more than 40 structural types, represent one of the largest natural product families that have …

A visible-light-induced synthesis of 3-acylindoles from simple indoles and α-oxo acids at
room temperature has been discovered. The reaction tolerates a wide range of functional …

Few natural oxindole alkaloids possess an exceptional spiro‐[(1, 3) oxazinan‐3, 6′‐
oxindole] core structure, which results from an unusual oxidative indole rearrangement. The …

A visible light‐induced, aerobic oxyamidation reaction of indoles, using air as the sole
oxidant, has been developed. This process serves as a photocatalytic strategy to generate …

A visible light-induced aerobic oxidative cross-coupling of glycine derivatives with indoles
has been developed to efficiently synthesize 3, 3′-bisindolylmethanes (BIMs). The reaction …

A tin-free method for the synthesis of substituted indolines has been developed generating
vinyl radicals by visible-light-promoted photocatalysis in a reductive quenching cycle. This …

The novel photoisomerization of 1-acylindoles accompanied by a conversion of indole to
indolenine afforded 3-acylindolenines, a so far unknown reactive species, as a major …

A facile approach toward 3-(o-aminophenyl) pyrroles was developed by remodeling of N-
sulfonyl-3-acyl indoles with N-phenylglycines under photoredox catalysis. This strategy …

In this work, a photocatalytic strategy for a rapid and modular access to polycyclic indolones
starting from readily available indoles is reported. This strategy relies on the use of redox …