Efficient hydrogenation of dimethyl oxalate to methyl glycolate over highly active immobilized-ruthenium catalyst

H Fan, J Tan, Y Zhu, H Zheng, Y Li - Journal of Molecular Catalysis A …, 2016 - Elsevier
Highly active and stable catalysts for hydrogenation of dimethyl oxalate (DMO) to methyl
glycolate (MG) were desirable but highly challengeable. In this study, a kind of immobilized …

Promoting effect of boron oxide on Ag/SiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate

H Chen, J Tan, J Cui, X Yang, H Zheng, Y Zhu, Y Li - Molecular Catalysis, 2017 - Elsevier
A highly active and stable catalyst for the hydrogenation of dimethyl oxalate (DMO) to methyl
glycolate (MG) had been developed. The Ag-B 2 O 3/SiO 2 catalysts were prepared by …

Highly selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over an amino-assisted Ru-based catalyst

L Song, Y He, C Zhou, G Shu, K Ma… - Chemical …, 2022 - pubs.rsc.org
A Ru/NH2-MCM-41 catalyst was prepared via a coordination-assisted strategy for
chemoselective hydrogenation of dimethyl oxalate with a high selectivity of methyl glycolate …

High activity and selectivity of Ag/SiO 2 catalyst for hydrogenation of dimethyl oxalate

A Yin, X Guo, W Dai, K Fan - Chemical communications, 2010 - pubs.rsc.org
Ag/SiO2 prepared by a sol–gel process is highly effective for selective gas-phase
hydrogenation of dimethyl oxalate to corresponding alcohols. The catalysts are of great …

Selective Hydrogenation of Dimethyl Oxalate to Methyl Glycolate over Boron-Modified Ag/SiO2 Catalysts

S Cheng, T Meng, D Mao, X Guo, J Yu - ACS omega, 2022 - ACS Publications
The addition of boron (B) as a promoter to the Ag/SiO2 catalyst for the selective
hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG) was investigated. A …

Synthesis of methyl glycolate via low‐temperature hydrogenation of dimethyl oxalate over an efficient and stable Ru/activated carbon catalyst

H Zheng, Y Xue, Y Niu, X Gao, Y Wang… - Journal of Chemical …, 2022 - Wiley Online Library
BACKGROUND Syngas to dimethyl oxalate (DMO) followed by hydrogenation to methyl
glycolate (MG) is considered to be an environmentally friendly and economical route …

Synthesis of methyl glycolate from the hydrogenation of dimethyl oxalate on Ag/SiO2 catalyst: the effects of Ag contents and promoters

S Cheng, D Mao, X Guo, J Yu - Reaction Kinetics, Mechanisms and …, 2019 - Springer
A series of silica supported silver catalysts (Ag/SiO 2) with Ag loading ranging from 5% to
15% were fabricated by the ammonia-evaporation deposition–precipitation method. The …

Facile synthesis of Cu@ Ag/SiO2 catalysts for the selective hydrogenation of dimethyl oxalate to methyl glycolate

Y Hai, T Guan, Y Feng, Z Zhen, Y Yang, Y Hu… - Chemical Engineering …, 2024 - Elsevier
A promising route for producing biodegradable polyglycolic acid material from syngas has
garnered increasing attentions. In this route, one of the pivotal issues is developing …

Cobalt-silver catalyst with low metal content for highly efficient synthesis of methyl glycolate through synergistic effect

F Zheng, J Gong, H Zhang, W Shu, X Wang… - Chemical Engineering …, 2024 - Elsevier
Abstract The Co-Ag x/TiO 2 catalysts with low mass content of Co and Ag were synthesized
through the impregnation method and investigated for dimethyl oxalate (DMO) …

Facile and Optimized Ion-Exchange Method for Synthesizing Low-Cost and Stable Cu/SiO2 Catalyst for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol

J Yang, L Lin, P Zhang, R Ye, Y Wang… - Industrial & …, 2023 - ACS Publications
A low-cost and stable Cu/SiO2 catalyst with a commercial SiO2 sphere support was
designed and prepared for vapor-phase hydrogenation of dimethyl oxalate (DMO) to …