Studies on sodium silicate solutions by the method of trimethylsilylation

LSD Glasser, EE Lachowski… - Journal of Applied …, 1977 - Wiley Online Library
The method of trimethylsilylation was used to study anion distributions in sodium silicate
solutions with Na2O: SiO2 ratios of 1: 1 and 1: 3.41 at various concentrations. The …

The constitution of aqueous silicate solutions

NH Ray, RJ Plaisted - Journal of the Chemical Society, Dalton …, 1983 - pubs.rsc.org
The distributions of anions in solutions of lithium, sodium, potassium, rubidium, caesium,
and tetramethyl-, tetra-n-propyl-, and tetra-n-butyl-ammonium silicate solutions have been …

Silylation of water glass. I. Solvent extraction and trimethylsilylation of silicic acid

S Kohama, H Inoue, T Yasuda - Journal of Polymer Science …, 1980 - Wiley Online Library
Homogeneous trimethylsilylation of silicic acid in nonaqueous media was studied. The
silylation process consisted of three steps: acidification of sodium silicate, solvent extraction …

The effect of tetramethylammonium ions on the distribution of silicate species in the methanolic solutions

I Hasegawa, S Sakka, K Kuroda, C Kato - Journal of molecular liquids, 1987 - Elsevier
The effect of the addition of tetramethylammonium ions on the distribution of silicate species
in the methanolic solutions was studied by the trimethylsilylation technique …

Colloidal components in solutions of sodium silicate

RK Iler - 1982 - ACS Publications
In concentrated solutions of sodium silicate with SiO2: Na2O ratios ranging from 2: 1 to 4: 1,
about 75% of the silica is present as extremely small particles which increase from 1 to 2 nm …

Polysilicate equilibria in concentrated sodium silicate solutions

IL Svensson, S Sjöberg, LO Öhman - Journal of the Chemical Society …, 1986 - pubs.rsc.org
Polysilicate equilibria in concentrated sodium silicate solutions have been studied using
potentiometric (glass electrode) and 29Si nmr methods. Experimental data cover the ranges …

Trimethylsilylation of mineral silicates

BR Currell, JR Parsonage - Journal of Macromolecular Science …, 1981 - Taylor & Francis
The application of the technique of trimethylsilylation to mineral silicates is reviewed.
Information can be obtained on the molecular size distribution of the silicate anions and also …

Experiences with the method of trimethylsilylation for the study of soluble silicates

LSD Glasser, SK Sharma - British Polymer Journal, 1974 - Wiley Online Library
It is possible to prepare organic derivatives of silicate groups in which each terminal oxygen
is blocked by a trimethylsilyl group. This can provide a route for the preparation of new …

Silicate species in solution. Part 1. Experimental observations

LSD Glasser, EE Lachowski - Journal of the Chemical Society, Dalton …, 1980 - pubs.rsc.org
Changes in the pH or concentration of sodium silicate solutions produce changes in the
degree of polymerisation of the silicate species, and these have been followed by the …

Determination of the changes of the basic structures of silica species in dependence on the concentration of sodium chloride by FAB-MS

M Tanaka, K Takahashi - Fresenius' journal of analytical chemistry, 2000 - Springer
The chemical species of silica in NaCl solutions of different concentrations were identified by
FAB-MS (fast atom bombardment mass spectrometry). The basic structures of silica species …