Visible light-induced intramolecular dearomative cyclization of α-bromo-N-benzyl-alkylamides: efficient construction of 2-azaspiro [4.5] decanes

B Hu, Y Li, W Dong, K Ren, X Xie, J Wan… - Chemical …, 2016 - pubs.rsc.org
Visible light-induced intramolecular dearomative cyclization of α-bromo- N -benzyl-alkylamides:
efficient construction of 2-azaspiro[4.5]decanes - Chemical Communications (RSC Publishing) …

Batch and flow photochemical benzannulations based on the reaction of ynamides and diazo ketones. Application to the synthesis of polycyclic aromatic and …

TP Willumstad, O Haze, XY Mak, TY Lam… - The Journal of …, 2013 - ACS Publications
Highly substituted polycyclic aromatic and heteroaromatic compounds are produced via a
two-stage tandem benzannulation/cyclization strategy. The initial benzannulation step …

Visible-light-induced 1, 6-enynes triggered C–Br bond homolysis of bromomalonates: solvent-controlled divergent synthesis of carbonylated and hydroxylated …

J Liu, S Tang, S Wang, M Cao, J Zhao… - The Journal of …, 2022 - ACS Publications
Visible-light-induced 1, 6-enyne-triggered C–Br bond homolysis of bromomalonates has
been developed. This transition-metal-free, photocatalyst-free, and oxidant-and additive-free …

Dearomative spirocyclization via visible-light-induced reductive hydroarylation of non-activated arenes

Z Chi, Y Gao, L Yang, C Zhou, M Zhang, P Cheng… - Chinese Chemical …, 2022 - Elsevier
A visible-light-induced spirocyclizative hydroarylation via reductive dearomatization of a
series of non-activated arenes including 2-phenyl indoles and naphthalene derivatives …

Photocatalytic Annulation‐Carbohalogenation of 1,7‐Enynes for Atom‐Economic Synthesis of Functionalized 3,4‐Dihydronaphthalen‐1(2H)‐ones

WZ Ji, HN Shi, P Wei, WJ Hao, SJ Tu… - Advanced Synthesis & …, 2021 - Wiley Online Library
A general and efficient photocatalytic annulation‐carbohalogenation of 1, 7‐enynes with a
wide variety of alkyl halides was reported, which led to the atom‐economic synthesis of …

Regioselective Dearomative Amidoximation of Nonactivated Arenes Enabled by Photohomolytic Cleavage of N‐nitrosamides

PF Yuan, XT Huang, L Long, T Huang… - Angewandte Chemie …, 2024 - Wiley Online Library
Dearomative spirocyclization reactions represent a promising means to convert arenes into
three‐dimensional architectures; however, controlling the regioselectivity of radical …

Nitrogen‐Radical‐Triggered Trifunctionalizing ipso‐Spirocyclization of Unactivated Alkenes with Vinyl Azides: A Modular Access to Spiroaminal Frameworks

Z Qi, Z Zhang, L Yang, D Zhang, J Lu… - Advanced Synthesis …, 2021 - Wiley Online Library
We report an example of non‐dearomative trifunctionalizing ipso‐spirocyclization of
unactivated alkenes through photoredox‐catalyzed, nitrogen‐radical‐triggered cyclization …

Photo-induced spirocyclization of biaryl ynones with ammonium thiocyanate: access to thiocyanate-featured spiro [5, 5] trienones

S Chen, Q Yan, J Fan, C Guo, L Li, ZQ Liu, Z Li - Green Chemistry, 2023 - pubs.rsc.org
Photo-promoted mild tandem 6-exo-trig spirocyclization of biaryl ynones with ammonium
thiocyanate has been developed to access thiocyanate-containing spiro [5, 5] trienones with …

Visible-light-induced intermolecular dearomative cyclization of furans: synthesis of 1-oxaspiro [4.4] nona-3, 6-dien-2-one

W Dong, Y Yuan, X Gao, M Keranmu, W Li… - The Journal of …, 2019 - ACS Publications
A fac-Ir (ppy) 3-catalyzed intermolecular dearomative cyclization of 2-bromo-2-((5-
bromofuran-2-yl) methyl) malonate and alkynes affording substituted spirolactones in yields …

Intramolecular Alkene Electrophilic Bromination Initiated ipso-Bromocyclization for the Synthesis of Functionalized Azaspirocyclohexadienones

Q Yin, SL You - Organic letters, 2012 - ACS Publications
Intramolecular Alkene Electrophilic Bromination Initiated ipso-Bromocyclization for the
Synthesis of Functionalized Azaspirocyclohexadienones | Organic Letters ACS ACS …