A new method for β-phenol annulation involving base-induced [4C+ 2C] cycloaromatization
of readily available 4-bis (methylthio)-3-buten-2-one with a variety of cyclic and acyclic …

This article describes the first application of 2-aminophenylboronates as precursors for
benzynes. Utilizing Rh2 (HNCOCF3) 4 as the catalyst, Rh (II)-nitrene-mediated N–H …

A facile construction of the spiro [indole-3, 2′-pyrrolidine] skeleton, through
diacetoxyiodobenzene (PIDA) mediated C–N bond-forming dearomatization of C3 …

A 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4-CzIPN)-photocatalyzed cascade
arylation/cyclization reaction of 2-isocyanobiaryls and iodonium ylides was established for …

The complex bioactive natural and unnatural benzopyran congeners have been synthesized
using one-/two-step approaches in very good yields from the reactions of two different …

Lewis base dependent (3+ 3) annulation of δ-acetoxy allenoates with benzofuranone,
pyrazolone, and Boc-protected oxindole is reported. In the presence of catalytic DBU …

In recent years, spirocyclic compounds have attracted a significant interest in medicinal
chemistry due to their considerable biological activities. The general and widely used …

DTBP‐Mediated Cascade Spirocyclization and Dearomatization of Biaryl Ynones: Facile Access
to Spiro[5.5]trienones through C(sp3)−H Bond Functionalization - Zhang - 2021 - European …

Dearomative photocycloaddition of monocyclic arenes is an appealing strategy for
comprehending the concept of “escape from flatland”. This brings the replacement of readily …

Synthesis of arylboronates via borylation of C–C σ-bonds of aryl ketones was achieved by
the combined use of photoenergy and a Rh catalyst. The cooperative system enables α …