Shock tube measurements of the rate constant for the reaction ethanol+ OH

I Stranic, GA Pang, RK Hanson… - The Journal of …, 2014 - ACS Publications
The overall rate constant for the reaction ethanol+ OH→ products was determined
experimentally from 900 to 1270 K behind reflected shock waves. Ethan18ol was utilized for …

Experimental Determination of the High-Temperature Rate Constant for the Reaction of OH with sec-Butanol

GA Pang, RK Hanson, DM Golden… - The Journal of Physical …, 2012 - ACS Publications
The overall rate constant for the reaction of OH with sec-butanol [CH3CH (OH) CH2CH3]
was determined from measurements of the near-first-order OH decay in shock-heated …

Rate constant measurements for the overall reaction of OH+ 1-butanol→ products from 900 to 1200 K

GA Pang, RK Hanson, DM Golden… - The Journal of Physical …, 2012 - ACS Publications
The rate constant for the overall reaction OH+ 1-butanol→ products was determined in the
temperature range 900 to 1200 K from measurements of OH concentration time histories in …

The reaction of hydroxyethyl radicals with O2: A theoretical analysis and experimental product study

J Zádor, RX Fernandes, Y Georgievskii… - Proceedings of the …, 2009 - Elsevier
Reactions of α-hydroxyethyl (CH3CHOH) and β-hydroxyethyl (CH2CH2OH) radicals with
oxygen are of key importance in ethanol combustion. High-level ab initio calculations of the …

High-Temperature Rate Constant Determination for the Reaction of OH with iso-Butanol

GA Pang, RK Hanson, DM Golden… - The Journal of Physical …, 2012 - ACS Publications
This work presents the first direct experimental study of the rate constant for the reaction of
OH with iso-butanol (2-methyl-1-propanol) at temperatures from 907 to 1147 K at near …

Site-specific rate coefficients for reaction of OH with ethanol from 298 to 900 K

SA Carr, MA Blitz, PW Seakins - The Journal of Physical Chemistry …, 2011 - ACS Publications
The rate coefficients for reactions of OH with ethanol and partially deuterated ethanols have
been measured by laser flash photolysis/laser-induced fluorescence over the temperature …

Rate constants for the thermal decomposition of ethanol and its bimolecular reactions with OH and D: reflected shock tube and theoretical studies

R Sivaramakrishnan, MC Su, JV Michael… - The Journal of …, 2010 - ACS Publications
The thermal decomposition of ethanol and its reactions with OH and D have been studied
with both shock tube experiments and ab initio transition state theory-based master equation …

[PDF][PDF] Thermochemistry and kinetics of the alpha-and beta-hydroxyethyl radical+ O2 reactions in ethanol combustion

G da Silva, JW Bozzelli, L Liang… - 5th US Combustion …, 2007 - researchgate.net
Bioethanol is emerging as a component that will be increasingly blended into traditional
petroleum-derived gasoline. It is important that we have accurate kinetic models for the …

Shock tube study of ethanol pyrolysis II: Rate constant measurements and modeling

R Choudhary, V Boddapati, S Clees, JJ Girard… - Combustion and …, 2021 - Elsevier
The rate constants of two unimolecular decomposition channels of ethanol, C 2 H 5 OH (+
Ar)= CH 3+ CH 2 OH (+ Ar), and C 2 H 5 OH (+ Ar)= C 2 H 4+ H 2 O (+ Ar) were measured …

[PDF][PDF] Multi-species time history measurements during ethanol pyrolysis behind reflected shock waves

R Choudhary, Y Peng, J Shao… - 11th US National …, 2019 - researchgate.net
Pyrolysis of ethanol was studied behind reflected shock waves at 10 atm in the Stanford
High-Pressure Shock Tube (HPST) facility, in the temperature range of 1200 K-1600 K …