Herein, we report a fully atom-economic and highly step-economic cascade dearomatization
with non-activated phenyl and other hetero-aryl rings for access to aniline-tethered spiro …

Photo-mediated radical dearomatization involving 5-exo-trig cyclizations has proven to be
an important route to accessing spirocyclic compounds, whereas 6-exo-trig spirocyclization …

We report an example of non‐dearomative trifunctionalizing ipso‐spirocyclization of
unactivated alkenes through photoredox‐catalyzed, nitrogen‐radical‐triggered cyclization …

Heterocyclic scaffolds are commonly found in numerous biologically active molecules,
therapeutic agents, and agrochemicals. To probe chemical space around heterocycles …

Here, we describe the recent progress toward construction of 1-azabicyclic structures using
a domino hydroformylation double cyclization strategy of an amide bearing the trisubstituted …

The dearomative cyclization of linear amides to complex spirocyclic butyrolactams has been
enabled by photoredox catalysis through a reductive radical–polar crossover mechanism …

Hydroarylation of alkenes has been demonstrated to be an atom-economic approach to
access functionalized arenes from easily accessible raw materials. Herein, we report a …

An unprecedented cascade dearomative cyclization through hydrogen-bonding-assisted
hydride transfer is realized. The aggregate effect of HFIP enables the rapid buildup of …

The construction of aromatic compounds from non-aromatic compounds via skeletal editing
is appealing yet challenging in organic chemistry. Herein, we report an approach for the …

Dearomatization and direct C (sp3)–H functionalization represent two hot research fields in
organic synthesis, the merging of which is among the most challenging but appealing topics …