[图书][B] The electronic structure of environmentally persistent free radicals formed on metal oxide surfaces

CA Thibodeaux - 2015 - search.proquest.com
We have investigated the electronic structure of environmentally persistent free radicals
(EPFRs) formed on two different metal oxides: Cu (II) O and ZnO. Cu (II) O is known to be …

Environmentally persistent free radicals readily form on TiO 2 but not on ZnO nanoparticles

EP Vejerano, J Ahn - Environmental Science: Nano, 2024 - pubs.rsc.org
Environmentally persistent free radicals (EPFRs) are stable organic radicals and pollutants
in atmospheric and soil particles. Knowledge of EPFR formation on pristine, unsupported …

Lifetime of combustion-generated environmentally persistent free radicals on Zn (II) O and other transition metal oxides

E Vejerano, S Lomnicki, B Dellinger - Journal of environmental …, 2012 - pubs.rsc.org
Previous studies indicated that Environmentally Persistent Free Radicals (EPFRs) are
formed in the post-flame, cool zone of combustion. They result from the chemisorption of gas …

Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation

MC Patterson, MF DiTusa, CA McFerrin, RL Kurtz… - Chemical physics …, 2017 - Elsevier
Environmentally persistent free radicals (EPFRs) have significant environmental and public
health impacts. In this study, we demonstrate that EPFRs formed on ZnO nanoparticles …

Formation Mechanism of Environmentally Persistent Free Radicals on Alkaline Earth Oxide Surfaces

D Liang, J Liu, Y Feng, K Tu, L Wang… - The Journal of …, 2024 - ACS Publications
The formation of environmentally persistent free radicals (EPFRs) is usually related to
transition-metal oxides in particulate matter (PM). However, recent studies suggest that …

Electronic Signatures of a Model Pollutant–Particle System: Chemisorbed Phenol on TiO2(110)

MC Patterson, CA Thibodeaux, O Kizilkaya, RL Kurtz… - Langmuir, 2015 - ACS Publications
Environmentally persistent free radicals (EPFRs) are a class of composite organic/metal
oxide pollutants that have recently been discovered to form from a wide variety of substituted …

Formation Mechanism of Environmentally Persistent Free Radicals during Soot Aging

D Liang, J Liu, F Bai, K Tu, L Wang, Z Wang, T He… - Atmospheric …, 2024 - Elsevier
Environmentally persistent free radicals (EPFRs) are a newly emerging class of pollutants
that are known to be formed on metal oxides (MOs). Recent experimental investigations …

Formation and stabilization of combustion-generated, environmentally persistent radicals on Ni (II) O supported on a silica surface

E Vejerano, SM Lomnicki… - Environmental science & …, 2012 - ACS Publications
Previous studies have indicated environmentally persistent free radicals (EPFRs) are formed
when hydroxyl-and chlorine-substituted aromatics chemisorbed on Cu (II) O and Fe (III) 2O3 …

[图书][B] Formation and stabilization of combustion-generated environmentally persistent free radicals on transition metal oxides supported on silica

EWP Vejerano - 2011 - search.proquest.com
The formation of environmentally persistent free radicals in combustion system was
investigated from chemisorptions of chlorine-and hydroxy-substituted benzenes on transition …

EPFR formation from phenol adsorption on Al2O3 and TiO2: EPR and EELS studies

MC Patterson, ND Keilbart, LW Kiruri, CA Thibodeaux… - Chemical physics, 2013 - Elsevier
We have examined the formation of environmentally persistent free radicals (EPFRs) from
phenol over alumina and titania using both powder and single-crystal samples. Electron …