An efficient synthesis of methylene-unsubstituted cyclopropane-fused indolines via
photoredox catalyzed dearomative cyclopropanation of indole derivatives was developed. A …

A photocatalytic protocol for the divergent dearomative functionalization of indole derivatives
is reported. Under the irradiation of visible light, either dimerization or reduction occurs …

Herein, we report a protocol for visible-light-induced dearomative oxamination reactions of
indole derivatives to afford functionalized spirocyclic products. These step-economical …

Dearomatization of indole derivatives offers a straightforward approach to access diverse
indolines. To date, the corresponding dearomative transformations involving electron …

Blue-light-mediated cyclopropanation of indoles with aryl (diazo) acetates has been
developed. The salient features of this strategy are that it is metal-free, operationally simple …

An intramolecular dearomatization of indole derivatives based on visible-light-promoted [2+
2] cycloaddition was achieved via energy transfer mechanism. The highly strained …

Dearomatization of indoles provides efficient synthetic routes for substituted indolines. In
most cases, indoles serve as nucleophiles. Reported here is an asymmetric dearomatization …

Expedient assembly of unprecedented molecular scaffolds from readily accessible starting
materials in a sustainable fashion is highly pursued in modern organic chemistry. Herein …

A facile and efficient asymmetric dearomative oxyalkylation of indoles with TEMPO
oxoammonium salt and a variety of aldehydes and ketones has been described. This metal …

Visible light-promoted dearomative [2+ 2] cycloaddition of indole derivatives tethered with
olefins at the N1 position has been considered thermodynamically unfeasible due to the …