Photocatalytic synthesis of polycyclic indolones

T Saget, B König - Chemistry–A European Journal, 2020 - Wiley Online Library
In this work, a photocatalytic strategy for a rapid and modular access to polycyclic indolones
starting from readily available indoles is reported. This strategy relies on the use of redox …

Tandem cyclisation of vinyl radicals: a sustainable approach to indolines utilizing visible-light photoredox catalysis

SK Pagire, O Reiser - Green Chemistry, 2017 - pubs.rsc.org
A tin-free method for the synthesis of substituted indolines has been developed generating
vinyl radicals by visible-light-promoted photocatalysis in a reductive quenching cycle. This …

Photoinduced synthesis of functionalized oxacyclic spirooxindoles via ring expansion

D Qi, J Bai, Z Song, B Li, C Yang, L Guo, W Xia - Organic Letters, 2023 - ACS Publications
A versatile photochemical ring-expansion protocol for the synthesis of oxacyclic
spirooxindoles under catalyst-free conditions is described. The reaction is enabled by the …

Transition Metal-Free, Methoxide-Catalyzed Synthesis of Pyridoindolones

S Park, JU Park, YL Kim, JH Kim - The Journal of Organic …, 2021 - ACS Publications
A simple transition metal-free strategy for the synthesis of pyrido [1, 2-a] indolone derivatives
has been devised through sodium methoxide-catalyzed intramolecular cyclization of 2 …

Synthesis of indolo [2, 1-a] isoquinoline derivatives via visible-light-induced radical cascade cyclization reactions

YL Wei, JQ Chen, B Sun, PF Xu - Chemical Communications, 2019 - pubs.rsc.org
We describe a photocatalyzed transformation for the synthesis of the indolo [2, 1-a]
isoquinoline core structure. This redox neutral reaction features mild reaction conditions and …

From benzopyrroles to phenylpyrroles: remodeling of indoles enabled by photoredox catalysis

W Xu, B Cheng, Y Zhang, L Fang, H Zhai… - Organic Chemistry …, 2023 - pubs.rsc.org
A facile approach toward 3-(o-aminophenyl) pyrroles was developed by remodeling of N-
sulfonyl-3-acyl indoles with N-phenylglycines under photoredox catalysis. This strategy …

Metal-Free Synthesis of Indolopyrans and 2, 3-Dihydrofurans Based on Tandem Oxidative Cycloaddition

S Choi, H Oh, J Sim, E Yu, S Shin, CM Park - Organic Letters, 2020 - ACS Publications
The synthesis of versatile scaffold indolopyrans based on C–C radical–radical cross-
coupling under metal-free conditions is described. The reaction involving single electron …

Synthesis of cyclobutane-fused angular tetracyclic spiroindolines via visible-light-promoted intramolecular dearomatization of indole derivatives

M Zhu, C Zheng, X Zhang, SL You - Journal of the American …, 2019 - ACS Publications
An intramolecular dearomatization of indole derivatives based on visible-light-promoted [2+
2] cycloaddition was achieved via energy transfer mechanism. The highly strained …

Tandem synthesis of polycyclic isoindoles

A Bornadiego, J Diaz, CF Marcos - The Journal of Organic …, 2019 - ACS Publications
We report an easy multicomponent synthesis of polycyclic isoindoles from cyclic 1, 3-
dicarbonyls, aldehydes, isocyanides, and maleimides. The key step consists of the one-pot …

Acylation of indoles via photoredox catalysis: a route to 3-acylindoles

L Gu, C Jin, J Liu, H Zhang, M Yuan, G Li - Green Chemistry, 2016 - pubs.rsc.org
A visible-light-induced synthesis of 3-acylindoles from simple indoles and α-oxo acids at
room temperature has been discovered. The reaction tolerates a wide range of functional …