The 7-coordinate complex [Fe (qpy)(MeCN) 2](ClO4) 2 (1, qpy= 2, 2′: 6′, 2 ″: 6 ″,
2′′′: 6′′′, 2′′′′-quinquepyridine) is a highly active nonheme iron catalyst for …

Iron‐Catalyzed Intramolecular Aminations of C(sp3)−H Bonds in Alkylaryl Azides - Alt - 2017 -
Angewandte Chemie International Edition - Wiley Online Library Skip to Article Content Skip to …

A catalytic system for intermolecular benzylic C (sp3)–H amination is developed utilizing 1,
2, 3, 4-tetrazole as a nitrene precursor via iron catalysis. This method enables direct …

Coordination of FeCl3 to the redox-active pyridine–aminophenol ligand NNO H2 in the
presence of base and under aerobic conditions generates FeCl2 (NNO ISQ)(1), featuring …

Formation of ubiquitous C–N bonds traditionally uses prefunctionalized carbon precursors.
Recently, metal-catalyzed amination of unfunctionalized C–H bonds with azides has …

Catalytic C− N bond formation by direct activation of C− H bonds offers wide synthetic
potential. En route to C− H amination, complexes with organic azides are critical precursors …

The direct catalytic transformation of typically inert carbon–hydrogen bonds into carbon–
oxygen, carbon–nitrogen, and carbon–carbon bonds represents a significant challenge in …

C− C bond formation reactions that take place through organoiron species sometimes
exhibit radical-like character. The reaction of N-(2-iodophenylmethyl) dialkylamine with a …

A concept for intramolecular denitrogenative C (sp3)–H amination of 1, 2, 3, 4-tetrazoles
bearing unactivated primary, secondary, and tertiary C–H bonds is discovered. This catalytic …

Transition‐metal‐catalyzed C—H bond amination reaction is an attractive method for the
synthesis of amines. Fueled by the growing interests in the development of economical and …