Combining spontaneous polymerization and click reactions for the synthesis of polymer brushes: A “grafting onto” approach

A Cappelli, G Grisci, M Paolino… - … A European Journal, 2013 - Wiley Online Library
Two novel benzofulvene monomers bearing propargyl or allyl groups have been
synthesized by means of readily accessible reactions, and were found to polymerize …

Supramolecular Polymer Brushes

FK Metze, HA Klok - ACS Polymers Au, 2023 - ACS Publications
Polymer brushes are thin polymer films that consist of densely grafted, chain-end tethered
polymers. These thin polymer films can be produced either by anchoring presynthesized …

Polymer brushes: efficient synthesis and applications

C Feng, X Huang - Accounts of chemical research, 2018 - ACS Publications
Conspectus Polymer brushes are special macromolecular structures with polymer chains
densely tethered to another polymer chain (one-dimensional, 1D) or the surface of a planar …

New methods in polymer brush synthesis: Non-vinyl-based semiflexible and rigid-rod polymer brushes

CJ Reese, SG Boyes - Progress in Polymer Science, 2021 - Elsevier
Non-vinyl-based 'grafted from'polymer brushes have generated much interest and growth in
the past decade due to the potential for stiffer backbones, long-range order, and new …

Towards controlled polymer brushes via a self-assembly-assisted-grafting-to approach

T Zhou, H Qi, L Han, D Barbash, CY Li - Nature communications, 2016 - nature.com
Precise synthesis of polymer brushes to modify the surface of nanoparticles and
nanodevices for targeted applications has been one of the major focuses in the community …

Synthesis of molecular brushes by “grafting onto” method: combination of ATRP and click reactions

H Gao, K Matyjaszewski - Journal of the American Chemical …, 2007 - ACS Publications
Molecular brushes (densely grafted polymers or bottle-brush macromolecules) were
synthesized by the “grafting onto” method via combination of atom transfer radical …

Synthesis of a cyclic-brush polymer with a high grafting density using activated ester chemistry via the “grafting onto” approach

S Zhang, X Cheng, J Wang, Z Zhang, W Zhang… - Polymer …, 2018 - pubs.rsc.org
In this work, novel cyclic-brush polymers with high grafting densities were successfully
constructed via the grafting onto approach by combining a light-induced Diels–Alder ring …

Cylindrical molecular brushes: Synthesis, characterization, and properties

SS Sheiko, BS Sumerlin, K Matyjaszewski - Progress in Polymer Science, 2008 - Elsevier
Brush-like macromolecules are unique polymer molecules whose conformation and
physical properties are controlled by steric repulsion of densely grafted side chains …

A click chemistry-based “grafting through” approach to the synthesis of a biorelevant polymer brush

A Cappelli, M Paolino, G Grisci, G Giuliani… - Polymer …, 2011 - pubs.rsc.org
A new biorelevant polymer brush showing a polybenzofulvene backbone was synthesized
by a “grafting through” approach based on click chemistry and spontaneous polymerization …

Recent advances in polymer brush synthesis

AM Granville, WJ Brittain - Polymer Brushes: Synthesis …, 2004 - Wiley Online Library
The formation of these tethered chains is generally carried out using either of two
techniques, namely physisorption or chemical bonding of chains to an interface. Typically …