On‐line control of emulsion polymerization reactors: A perspective

JM Asua - The Canadian Journal of Chemical Engineering, 2023 - Wiley Online Library
Emulsion polymerization is the method of choice to produce a wide range of specialty
waterborne polymer dispersions. These are multicharacteristic products that should meet …

Control of emulsion polymerization reactors

J Dimitratos, G Elicabe, C Georgakis - AIChE journal, 1994 - Wiley Online Library
The interest in emulsion polymerization is strong because it offers the possibility of
producing products with special properties not easily produced by other types of …

Feedback control of emulsion polymerization reactors: a critical review and future directions

JR Leiza, JM Asua - Polymeric Dispersions: Principles and Applications, 1997 - Springer
In the production of dispersed polymers, the main objectives to be fulfilled are: a) Safety. The
reactor temperature must be kept under safe limits to avoid thermal runaways. In addition …

Operation of semi-batch emulsion polymerisation reactors: Modelling, validation and effect of operating conditions

J Zeaiter, JA Romagnoli, GW Barton, VG Gomes… - Chemical Engineering …, 2002 - Elsevier
A detailed dynamic model was developed for a styrene emulsion polymerisation semi-batch
reactor to predict the evolution of the product particle size distribution (PSD) and molecular …

Dynamic optimization and experimental validation of a pilot scale emulsion polymerization reactor

AA Herrera, B Raba, G Rodríguez, ID Gil - Chemical Engineering and …, 2019 - Elsevier
Dynamic optimization of the emulsion polymerization of vinyl acetate in a pilot scale stirred-
tank reactor was studied. The objective function was defined in order to minimize the …

Reactor concepts for continuous emulsion polymerization

W Pauer - Polymer Reaction Engineering of Dispersed Systems …, 2018 - Springer
Emulsion polymers are products by process. Besides the process and recipe conditions the
reactor itself is the main factor that determines the product properties. In today's industrial …

[引用][C] Emulsion polymerization

JC De La Cal, JR Leiza, JM Asua… - … of Polymer Reaction …, 2005 - Wiley Online Library
This chapter contains sections titled: Introduction Features of Emulsion Polymerization
Alternative Polymerization Techniques Kinetics of Emulsion Polymerization Molecular …

Closed-loop in-silico control of a two-stage emulsion polymerization to obtain desired particle morphologies

JMM Faust, S Hamzehlou, JR Leiza, JM Asua… - Chemical Engineering …, 2021 - Elsevier
Particle morphology strongly affects the performance of waterborne polymer dispersions,
which are products-by-process materials produced by emulsion polymerization, a process …

On‐line monitoring, modeling, and model validation of semibatch emulsion polymerization in an automated reactor control facility

V Liotta, ED Sudol, MS El‐Aasser… - Journal of Polymer …, 1998 - Wiley Online Library
The modeling of the semibatch emulsion polymerization of styrene and its validation against
data obtained from a reactor facility is presented. The model, which describes the growth of …

Modeling and process optimization of a full-scale emulsion polymerization reactor

S Copelli, M Barozzi, N Petrucci, VC Moreno - Chemical Engineering …, 2019 - Elsevier
One of the most common but promising processes for the production of paints and coatings
is the free radical emulsion polymerization reaction involving different types of monomers …