Density-functional theory study on hydrogenation of dimethyl oxalate to methyl glycolate over copper catalyst: Effect of copper valence state

J An, X Wang, J Zhao, S Jiang, Y Quan, Y Pei, M Wu… - Molecular …, 2020 - Elsevier
The development of high-performance copper (Cu)-based catalysts is critical to achieve the
industrial hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG). To understand …

Studies on role of support metal in glycerol conversion to glycerol carbonate through Mg/MnO2 and Mg/CuO heterogeneous catalyst

S Jaiswal, S Maurya, YC Sharma - Molecular Catalysis, 2023 - Elsevier
Glycerol carbonate (GlyC) is desirable compound among numerous value-added products
produced from surplus waste glycerol coming from biodiesel industry. Because of its …

Design and Development of Cu− Zn Oxide Catalyst for Direct Dimethyl Ether Synthesis Using an Artificial Neural Network and Physicochemical Properties of Elements

K Omata, Sutarto, M Hashimoto… - Industrial & …, 2006 - ACS Publications
A hybrid catalyst consisting of Cu− Zn− X oxide and γ-alumina was prepared for single-stage
dimethyl ether synthesis. An artificial neural network (ANN) was applied to find the effective …

ZnxMg1‐xO Solid Solutions: Efficient Bifunctional Acid‐Base Catalyst for the synthesis of Methyl Ethyl Oxalate from Dimethyl Oxalate and Ethanol

H Wang, K Shao, H Jiang, C Wang, X Ma… - …, 2023 - Wiley Online Library
ZnO‐MgO composite catalysts were prepared by the coprecipitation method and used for
the synthesis of methyl ethyl oxalate (EMO) from dimethyl oxalate (DMO) and ethanol …

Reaction kinetics determination and neural networks modeling of methanol dehydration over nano γ-Al2O3 catalyst

S Alamolhoda, M Kazemeini, A Zaherian… - Journal of Industrial and …, 2012 - Elsevier
In this research nano γ-Al2O3 catalyst was synthesized through precipitation process then
characterized and utilized for methanol dehydration reaction in a slurry batch reactor in route …

[HTML][HTML] Kinetic modeling of conversion of glycerol to 1, 2-propanediol over bifunctional LDH catalyst

ML Meena, H Malviya, NN Pandhare… - Current Research in Green …, 2022 - Elsevier
The performance of a highly efficient Cu 0.45 Zn 0.15 Mg 5.4 Al 2 O 9 catalyst was
investigated using a high-pressure autoclave reactor by adjusting several reaction …

Toward rational catalyst design for partial hydrogenation of dimethyl oxalate to methyl glycolate: a descriptor-based microkinetic analysis

WQ Yan, JB Zhang, L Xiao, YA Zhu, YQ Cao… - Catalysis Science & …, 2019 - pubs.rsc.org
Partial hydrogenation of dimethyl oxalate (DMO) has attained increasing attention in the
chemical industry, which is driven by the desire to develop a means of achieving methyl …

Preparation and characterization of CuOAl2O3 catalyst for dimethyl ether production via methanol dehydration

CL Chiang, KS Lin - International journal of hydrogen energy, 2017 - Elsevier
In the present study, a CuOsingle bondAl 2 O 3 catalyst with CuAl 2 O 4 spinel structure was
prepared by a co-precipitation method and used for dimethyl ether (DME) production via …

Synthesis of methyl glycolate by hydrogenation of dimethyl oxalate with a P modified Co/SiO 2 catalyst

Z Zhuang, Y Li, F Chen, X Chen, Z Li, S Wang… - Chemical …, 2022 - pubs.rsc.org
A P-modified Co/SiO2 catalyst was reported for the first time in the selective hydrogenation
of dimethyl oxalate (DMO) to methyl glycolate (MG) reaction and the synthesized Co8P/SiO2 …

Modelling and simulation of hydrogenation of dimethyl oxalate in ethylene glycol production

FS Rohman, SHS Sulaiman, N Aziz - IOP Conference Series …, 2020 - iopscience.iop.org
In this work, the production of ethylene glycol was studied through a syngas-derived
ethylene glycol route known as the indirect syngas-to-ethylene glycol process via oxalates …