Thermolytic synthesis of imprinted amines in bulk silica

JD Bass, A Katz - Chemistry of materials, 2003 - ACS Publications
The synthesis of bulk, hydrophilic imprinted silica is reported via a novel method relying on
the thermolysis of carbamates. This method is used to synthesize single-site materials …

Bifunctional surface imprinting of silica: Thermolytic synthesis and characterization of discrete thiol− amine functional group pairs

JD Bass, A Katz - Chemistry of materials, 2006 - ACS Publications
In this article we demonstrate the sub-nanometer patterning of mixed chemical functional
groups consisting of thiol and primary amine functionality on the surface of silica and …

Silylated melamine and cyanuric acid as precursors for imprinted and hybrid silica materials with molecular recognition properties

G Arrachart, C Carcel, P Trens… - … A European Journal, 2009 - Wiley Online Library
Imprinted materials: Monosilylated derivatives of melamine and cyanuric acid are used in
the preparation of hybrid silica. The assembly of the melamine and cyanuric acid moieties …

Controlling morphology and porosity to improve performance of molecularly imprinted sol–gel silica

JE Lofgreen, GA Ozin - Chemical Society Reviews, 2014 - pubs.rsc.org
The wealth of molecular precursors for organic and inorganic polymers has resulted in an
incredible volume of molecular imprinting literature. The vast majority of reports deal with …

Molecularly imprinted mesoporous organosilica

JE Lofgreen, IL Moudrakovski, GA Ozin - ACS nano, 2011 - ACS Publications
We have prepared molecularly imprinted mesoporous organosilica (MIMO) using a
semicovalent imprinting technique. A thermally reversible covalent bond was used to link a …

Preparation and utilization of molecularly imprinted silicas

C Pinel, P Loisil, P Gallezot - Advanced Materials, 1997 - Wiley Online Library
Imprinted amorphous silicas tailored to adsorb selectively are presented. Their preparation–
using molecular imprinting by the sol‐gel technique–is described and the influence of the …

Molecular imprinting of bulk, microporous silica

A Katz, ME Davis - Nature, 2000 - nature.com
Molecular imprinting aims to create solid materials containing chemical functionalities that
are spatially organized by covalent or non-covalent interactions with imprint (or template) …

Biomimetic catalysis at silicon centre using molecularly imprinted polymers

V Abbate, AR Bassindale, KF Brandstadt, PG Taylor - Journal of Catalysis, 2011 - Elsevier
The first example of biomimetic siloxane bond formation catalyzed by molecularly imprinted
polymers (MIPs) is reported. MIPs were prepared by free-radical polymerization and …

[PDF][PDF] A historical perspective of the development of molecular imprinting

HS Andersson, IA Nicholls - … : Man-Made Mimics of Antibodies and …, 2001 - academia.edu
Here we review the history of molecular imprinting, from the introduction of the technique in
conjunction with silica matrices in 1931 until the beginning of the 1970s, when the technique …

Polymerizable amidines—Adhesion mediators and binding sites for molecular imprinting

G Wulff, R Schönfeld - Advanced Materials, 1998 - Wiley Online Library
New styryl amidines have been found to be the first easily polymerizable amidine
monomers. The effect of incorporation of these amidines in copolymers and the use of …