Recent advances in metal-catalysed asymmetric sequential double hydrofunctionalization of alkynes

Z Cheng, J Guo, Z Lu - Chemical Communications, 2020 - pubs.rsc.org
In recent years, metal-catalysed asymmetric sequential double hydrofunctionalization of
alkynes (ASDHA) has emerged as a powerful strategy to construct valuable chiral products …

Transition-metal catalyzed enantioselective hydrofunctionalization of alkynes

Y Zheng, W Zi - Tetrahedron Letters, 2018 - Elsevier
A significant number of reactions regarding hydrofunctionalization of alkynes have appeared
in the literature over the years. This digest focus on the transition-metal catalyzed …

Coordination Assistance: A Powerful Strategy for Metal-Catalyzed Regio-and Enantioselective Hydroalkynylation of Internal Alkenes

W Zhao, HX Lu, WW Zhang, BJ Li - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Alkenes are versatile compounds that are readily available on a large scale
from industry or through organic synthesis. The widespread occurrence of alkenes provides …

Iron-and cobalt-catalyzed asymmetric hydrofunctionalization of alkenes and alkynes

J Guo, Z Cheng, J Chen, X Chen… - Accounts of chemical …, 2021 - ACS Publications
Conspectus Transition metal catalyzed asymmetric hydrofunctionalization of readily
available unsaturated hydrocarbons presents one of the most straightforward and atom …

Asymmetric synthesis of allylic compounds via hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes

G Li, X Huo, X Jiang, W Zhang - Chemical Society Reviews, 2020 - pubs.rsc.org
Hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes are widely
utilized in the synthesis of valuable allylic compounds. In the past decades, asymmetric …

Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

J Chen, Z Lu - Organic Chemistry Frontiers, 2018 - pubs.rsc.org
In recent years, earth-abundant transition metal catalysts have been used to make great
achievements on homogenous catalysis, including the field of enantioselective …

Control of axial chirality through NiH-catalyzed atroposelective hydrofunctionalization of alkynes

FT Sheng, SC Wang, J Zhou, C Chen, Y Wang… - ACS …, 2023 - ACS Publications
Catalytic asymmetric hydrofunctionalization of alkenes is a well-established method with
which to construct complex C (sp3)-enriched molecules with central chirality. In contrast, the …

Asymmetric formal sp2-hydrocarbonations of dienes and alkynes via palladium hydride catalysis

MQ Tang, ZJ Yang, ZT He - Nature Communications, 2023 - nature.com
Transition metal-catalyzed asymmetric hydrofunctionalizations of unsaturated bonds via π-
ƞ3 substitution have emerged as a reliable method to construct stereogenic centers, and …

Asymmetric and switchable divergent multicomponent reactions involving distinct alkynes via palladium catalysis

Z Zhao, JL Zheng, W Du, YC Chen - Chem Catalysis, 2022 - cell.com
Asymmetric multicomponent reactions represent an efficient and economic strategy for the
construction of complicated structures, and those involving two different alkynes have been …

Desymmetrization of unactivated bis-alkenes via chiral Brønsted acid-catalysed hydroamination

ZL Yu, YF Cheng, NC Jiang, J Wang, LW Fan… - Chemical …, 2020 - pubs.rsc.org
Although great success has been achieved in catalytic asymmetric hydroamination of
unactivated alkenes using transition metal catalysis and organocatalysis, the development …