Synthesis of molecular brushes by “grafting onto” method: combination of ATRP and click reactions

H Gao, K Matyjaszewski - Journal of the American Chemical …, 2007 - ACS Publications
Molecular brushes (densely grafted polymers or bottle-brush macromolecules) were
synthesized by the “grafting onto” method via combination of atom transfer radical …

Initiation efficiency in the synthesis of molecular brushes by grafting from via atom transfer radical polymerization

BS Sumerlin, D Neugebauer, K Matyjaszewski - Macromolecules, 2005 - ACS Publications
Grafting from via atom transfer radical polymerization (ATRP) was employed for the
synthesis of densely grafted molecular brushes. A poly (2-(2-bromopropionyl) oxyethyl …

Molecular brushes with spontaneous gradient by atom transfer radical polymerization

H Lee, K Matyjaszewski, S Yu, SS Sheiko - Macromolecules, 2005 - ACS Publications
Spontaneous gradient copolymers were synthesized by atom transfer radical polymerization
(ATRP) of acrylates and methacrylates and were subsequently employed to prepare …

Synthesis of molecular brushes with block copolymer side chains using atom transfer radical polymerization

HG Börner, K Beers, K Matyjaszewski, SS Sheiko… - …, 2001 - ACS Publications
Brush macromolecules having poly (n-butyl acrylate-block-styrene) and poly (styrene-block-
n-butyl acrylate) side chains have been synthesized by the “grafting from” approach using …

Facile syntheses of cylindrical molecular brushes by a sequential RAFT and ROMP “grafting‐through” methodology

Z Li, K Zhang, J Ma, C Cheng… - Journal of Polymer …, 2009 - Wiley Online Library
Of significant interest is the development of synthetic methodologies to prepare complex
macromolecular structures that contain functionalities, allowing for stimuli-responsive …

Amphiphilic cylindrical core− shell brushes via a “grafting from” process using ATRP

G Cheng, A Böker, M Zhang, G Krausch… - …, 2001 - ACS Publications
Atom transfer radical polymerization (ATRP) was applied to the synthesis of amphiphilic
cylindrical polymer brushes by using the “grafting from” technique. The procedure included …

Effect of initiation conditions on the uniformity of three-arm star molecular brushes

K Matyjaszewski, S Qin, JR Boyce… - …, 2003 - ACS Publications
A series of three-arm star densely grafted molecular brushes with poly (n-butyl acrylate) side
chains were prepared by atom transfer radical polymerization (ATRP). The three-arm …

[引用][C] One-Pot Tandem Synthesis of a Core− Shell Brush Copolymer from Small Molecule Reactants by Ring-Opening Metathesis and Reversible Addition …

C Cheng, E Khoshdel, KL Wooley - Macromolecules, 2007 - ACS Publications
As an important type of nanoscopically sized single macromolecule, brush copolymers have
attracted significant attention due to their special properties and interest in the development …

Synthesis and visualization of densely grafted molecular brushes with crystallizable poly (octadecyl methacrylate) block segments

S Qin, K Matyjaszewski, H Xu, SS Sheiko - Macromolecules, 2003 - ACS Publications
Densely grafted molecular brushes with AB and ABA “block− graft” architectures, ie, pODMA-
bp (BPEM-gn BuA) and pODMA-bp (BPEM-gn BuA)-b-pODMA, were synthesized by the …

Synthesis of surface-initiated stimuli-responsive diblock copolymer brushes utilizing a combination of ATRP and RAFT polymerization techniques

MD Rowe, BAG Hammer, SG Boyes - Macromolecules, 2008 - ACS Publications
The synthesis of diblock copolymer brushes, including poly (styrene)(PSty)-b-PSty, PSty-b-
poly (acrylic acid), PSty-b-poly (N-isopropylacrylamide), and poly (methyl acrylate)-b-poly …