The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the
field of natural product synthesis. MHAT, as a powerful method, has been employed by …

This review highlights the most recent reports in three powerful and ever-growing fields of
borrowing hydrogen, acceptorless dehydrogenative coupling, and base-mediated hydride …

Conspectus The implementation of any chemical reaction in a structurally complex setting
(King, SMJ Org. Chem. 2014, 79, 8937) confronts structurally defined barriers: steric …

The first-row transition-metal-catalyzed hydrogen atom transfer reaction has emerged as a
practical synthetic platform for alkene hydrofunctionalization with high chemo-and …

Hydrogen-atom transfer mediated by earth-abundant transition-metal hydrides (M-Hs) has
emerged as a powerful tool in organic synthesis. Current methods to generate M-Hs most …

The use of isocyanides as acceptor groups in metal–hydride hydrogen atom transfer (MHAT)
coupling reactions with nonactivated alkenes to form heterocycles is described …

Abstract Development in the area of acceptorless dehydrogenation (AD) and borrowing
hydrogen (BH) catalysis emerge as one of the potential tools for various C− C and C …

Conspectus Traditional organic synthesis relies heavily on the transformations of various
preinstalled functional groups, such as cross-coupling reactions using organohalides and …

Catalytic metal hydride hydrogen atom transfer (MHAT) reactions have proven to be a
powerful method for alkene functionalization. This work reports the discovery of Co …

Catalyst controlled site-selective C–H functionalization is a challenging but powerful tool in
organic synthesis. Polarity-matched and sterically controlled hydrogen atom transfer (HAT) …