Reactivating catalytic surface: Insights into the role of hot holes in plasmonic catalysis

T Peng, J Miao, Z Gao, L Zhang, Y Gao, C Fan, D Li - Small, 2018 - Wiley Online Library
surfaces that recovers its catalytic activity. We suggested that hot electrons and hot holes
the different contributions from hot electrons and hot holes to the enhanced catalytic activity. We …

The effect of hot electrons and surface plasmons on heterogeneous catalysis

SM Kim, SW Lee, SY Moon… - Journal of Physics …, 2016 - iopscience.iop.org
role of hot electrons on atomic and molecular processes. The close correlation between hot
electron flow and catalytic … electron acceptor state (or hot holes can transfer into donor states) …

Hot-electron-mediated surface chemistry: toward electronic control of catalytic activity

JY Park, SM Kim, H Lee… - Accounts of chemical …, 2015 - ACS Publications
… , exothermic reactions catalyzed on metals can generate hot electrons and holes. These …
As additional key elements, we investigated the role of hot carriers generated on diverse …

[HTML][HTML] Plasmon-induced hot-hole generation and extraction at nano-heterointerfaces for photocatalysis

M Ahlawat, D Mittal, V Govind Rao - Communications Materials, 2021 - nature.com
hot holes by exploring different interfaces through which energetic holes can be localized to
the catalytic surface … transfer and hole transfer reaction yield validates the importance of hole

Increasing reactivity of plasmonic hot holes by a trapping strategy

C Li, Z Ma, B Han - Applied Catalysis B: Environmental, 2022 - Elsevier
… and holes by conducting electrons at the surface of gold nanoparticles (Au NPs) through … ),
confirming that plasmon-induced hot holes play a vital role in photocatalytic degradation of MB…

The pivotal role of hot carriers in plasmonic catalysis of C− N bond forming reaction of amines

S Swaminathan, VG Rao, JK Bera… - Angewandte …, 2021 - Wiley Online Library
… utilization of both the hot carriers (electrons and holes) in the … been successfully demonstrated
with catalytic oxidation of 4-… as both light absorber and catalytic surface in the oxidative …

Engineering the surface charge states of nanostructures for enhanced catalytic performance

Y Bai, H Huang, C Wang, R Long… - Materials Chemistry …, 2017 - pubs.rsc.org
… Upon identifying the importance of surface charge states to catalysis, a question naturally …
energetic electrons and holes, which are commonly referred to as hot electrons and hot holes, …

Visible light-promoted plasmon resonance to induce “hothole transfer and photothermal conversion for catalytic oxidation

J Boltersdorf, GT Forcherio, JP McClure… - The Journal of …, 2018 - ACS Publications
… ) UV-driven electron–hole separation of the TiO 2 SC and (B) “hot” electron transfer between
… are reduced by “hot” electrons on the TiO 2 surface and oxidized by “hotholes on the AuNP…

Electrically enhanced hot hole driven oxidation catalysis at the interface of a plasmon–exciton hybrid

W Lin, E Cao, L Zhang, X Xu, Y Song, W Liang, M Sun - Nanoscale, 2018 - pubs.rsc.org
… Our experimental results strongly support the main mechanism that hot holes drive surface
In the reduction reaction, plasmonic hot electrons play the main role, 36 while in the oxidation …

Hot electron and surface plasmon-driven catalytic reaction in metal–semiconductor nanostructures

JY Park, SM Kim, H Lee, B Naik - Catalysis letters, 2014 - Springer
… is a longstanding question of both fundamental and practical importance. Recent studies
have also demonstrated that hot charge carriers (eg, hot electrons or hot holes) control …