High-performance polysiloxane-based photorefractive polymers with nonlinear optical azo, stilbene, and tolane chromophores

S Schloter, U Hofmann, P Strohriegl, HW Schmidt… - JOSA B, 1998 - opg.optica.org
… on the incorporated nonlinear-optical chromophores. We compare three polysiloxane-… ,
and a tolane type of chromophore. Characteristic properties such as diffraction efficiency η, gain …

Highly fluorescent mono‐substituted poly (arylacetylene) s containing tolane chromophores

CC Han, A Balasubramanian - Journal of Polymer Science Part …, 2008 - Wiley Online Library
… even higher potential PL efficiency, if the simple tolane pendant group is replaced by its higher
… poly(phenylene ethynylene)s that are renowned with their extremely high PL efficiency.14 …

Crystallization-induced emission enhancement of a simple tolane-based mesogenic luminogen

J Tong, YJ Wang, Z Wang, JZ Sun… - The Journal of Physical …, 2015 - ACS Publications
… Such molecular conformation and chromophore packing eliminate the intermolecular π–π
interaction thereby greatly reducing the π–π interaction that caused fluorescence quenching, …

Photopolymers for non‐linear optics: Design and synthesis of a polymer containing styrene‐terminated tolane chromophores and its stabilization in an oriented …

A Godt, JMJ Fréchet, JE Beecher… - … Chemistry and Physics, 1995 - Wiley Online Library
… with pendant tolane nonlinear optical chromophores that … on the mobility of the chromophores
has been studied by … to NLO materials with highly stable chromophore orientation. …

High-performance material for holographic gratings by means of a photoresponsive polymer liquid crystal containing a tolane moiety with high birefringence

S Yoneyama, T Yamamoto, O Tsutsumi… - …, 2002 - ACS Publications
… T-AB clearly exhibited two bands at about 330 and 380 nm, stemming from the mesogen
and the chromophore, respectively. Homogeneously aligned films with thickness between 600 …

Bridged tolanes: A twisted tale

S Menning, M Krämer, A Duckworth… - The Journal of …, 2014 - ACS Publications
… (5) Influencing the rotational motion of these linear chromophores is a significant tool to …
The higher HOMO–LUMO gap in a fully twisted tolane leads to the observed hypsochromic shift …

Fabrication of highly efficient coatable polarizer from tolane-based smectic reactive mesogen

R He, E Oh, Y Ye, P Wen, KU Jeong, SH Lee, XD Li… - Polymer, 2019 - Elsevier
… to the average orientation of long axis of dye chromophores, respectively. T ∥ and T ⊥ are
… the average orientation of long axis of dye chromophores, respectively. For all the samples, …

Second‐order nonlinear optical properties and relaxation characteristics of poled linear epoxy polymers with tolane chromophores

D Jungbauer, I Teraoka, DY Yoon, B Reck… - Journal of applied …, 1991 - pubs.aip.org
… Reflecting a longer conjugation length, the absorption peak of tolane chromophores at
418 nm is red-shifted by 26 nm as compared with the absorption peak of nitroaniline chro…

A Tethered Tolane: Twisting the Excited State

Y Kozhemyakin, M Krämer, F Rominger… - … A European Journal, 2018 - Wiley Online Library
tolane, is an important fundamental chromophore in organic and polymer chemistry.1 Linear
and cyclic oligomers as well as tolane-… In solution tolane features a minute rotational barrier (…

Improved characterization of chromophores for photorefractive applications

CR Moylan, R Wortmann, RJ Twieg, IH McComb - JOSA B, 1998 - opg.optica.org
… solutions and on similar solutions of diphenylacetylene (tolane). The probe beam is … from
the chromophore or the tolane standard. The I -versus- w data for both the chromophore and …