… began our kinetic studies to determine rate constants for cyclization of alkyl radicals onto
C=… of the hydrazone was higher than that of the imine as predicted. It is anticipated that the …

… addition onto carbon–nitrogen double-bonds typically involve alkyl radicals and, to a lesser,
extent vinyl radicals… is still favoured slightly from a kinetic perspective. However, with a …

… and tertiary alkyl radicals in which the relative kinetic preference … in the last decades, radical
additions to imines have been … Intramolecular attack from radicals to imines is a synthetically …

… to achieve the intermolecular radical addition to 1. 9b,d,e More recently, we reported that
electron-deficient N-sulfonyl imine 3 exhibits an excellent reactivity and the radical addition to 3 …

… formal addition reaction to imines through radical processes … performed under an inter- or
intramolecular fashion [13]. The … developed an oxidative kinetic resolution reaction using chiral …

… regular variations of preexponential factors for the intermolecular addition of alkyl radicals
to … In fact, according to recent kinetic studies, cyclization of a secondary radical would be …

… in radical cyclizations to CN bonds, and intermolecular … Unfortunately, since the relevant
kinetic data are mostly … from a practical viewpoint, alkyl radical additions to alkenes are …

… imine acceptors have received increased scrutiny. Earlier we reported our results of a radical
… the extensive literature containing kinetic information on free radical additions onto carbon−…

… The addition of nucleophilic C-centered alkyl radicals to … kinetic studies are clearly required
to obtain full insight into … (radical) and HOMO (imine), which is the actual radical cyclization, to …

… alkyl radical adds to the C-atom of the imine formed in situ and activated towards nucleophilic
radical addition … that the Porta-type intermolecular addition of carbon radicals is indeed …