2-Quinoxalinol diamine Cu (II) complex: facilitating catalytic oxidation through dual mechanisms
Dalton Transactions, 2014•pubs.rsc.org
The Cu (II) complex 1, Cu (II)-6-N-3, 5-di-tert-butylsalicylidene-6, 7-quinoxalinol-diamine,
has been developed to address problems with current methods of catalytic oxidation using
tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize
TBHP while limiting interference from free radical reactions and was demonstrated to be
highly effective in the oxidations of a variety of olefins.
has been developed to address problems with current methods of catalytic oxidation using
tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize
TBHP while limiting interference from free radical reactions and was demonstrated to be
highly effective in the oxidations of a variety of olefins.
The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP while limiting interference from free radical reactions and was demonstrated to be highly effective in the oxidations of a variety of olefins.
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