A Ditopic Calix[6]arene Ligand with N-Methylimidazole and 1,2,3-Triazole Substituents: Synthesis and Coordination with Zn(II) Cations
B Colasson, M Save, P Milko, J Roithová… - Organic …, 2007 - ACS Publications
B Colasson, M Save, P Milko, J Roithová, D Schröder, O Reinaud
Organic Letters, 2007•ACS PublicationsThe first member of a new class of ditopic calix [6] arene has been synthesized, which is
decorated with three N-methylimidazoles at the small rim and three 1, 4-disubstituted-1, 2, 3-
triazoles at the large rim. The coordination of a first Zn (II) cation selectively takes place at
the small rim. Addition of a second equivalent results in the complexation of the three
triazoles, providing a rare example of 1, 2, 3-triazole ligands embedded within a
supramolecular system.
decorated with three N-methylimidazoles at the small rim and three 1, 4-disubstituted-1, 2, 3-
triazoles at the large rim. The coordination of a first Zn (II) cation selectively takes place at
the small rim. Addition of a second equivalent results in the complexation of the three
triazoles, providing a rare example of 1, 2, 3-triazole ligands embedded within a
supramolecular system.
The first member of a new class of ditopic calix[6]arene has been synthesized, which is decorated with three N-methylimidazoles at the small rim and three 1,4-disubstituted-1,2,3-triazoles at the large rim. The coordination of a first Zn(II) cation selectively takes place at the small rim. Addition of a second equivalent results in the complexation of the three triazoles, providing a rare example of 1,2,3-triazole ligands embedded within a supramolecular system.
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