A highly stable porphyrinic zirconium metal–organic framework with shp-a topology
Through a kinetically controlled synthetic process, we synthesized PCN-223, a new
porphyrinic Zr-MOF constructed from the newly reported hexagonal prismatic 12-connected
Zr6 cluster through an unusual disordered arrangement, giving rise to the first example of
the shp-a network in MOFs. With its extremely high connectivity, PCN-223 shows high
stability in aqueous solutions with a wide range of pH. Cationic PCN-223 (Fe) formed by
postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero …
porphyrinic Zr-MOF constructed from the newly reported hexagonal prismatic 12-connected
Zr6 cluster through an unusual disordered arrangement, giving rise to the first example of
the shp-a network in MOFs. With its extremely high connectivity, PCN-223 shows high
stability in aqueous solutions with a wide range of pH. Cationic PCN-223 (Fe) formed by
postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero …
[引用][C] A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology
F Dawei, G Zhi-Yuan, C Ying-Pin, P Jihye… - 2014
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