A luminescent and biocompatible PhotoCORM
AE Pierri, A Pallaoro, G Wu… - Journal of the American …, 2012 - ACS Publications
The water-soluble rhenium (I) complex fac-[Re (bpy)(CO) 3 (thp)]+(1)[CF3SO3–salt; bpy= 2,
2′-bipyridine, thp= tris (hydroxymethyl) phosphine] is both strongly luminescent and
photoactive toward carbon monoxide release. It is stable in aerated aqueous media, is
incorporated into cells from the human prostatic carcinoma cell line PPC-1, and shows no
apparent cytotoxicity. Furthermore, the solvated Re (I) photoproduct of CO release (2) is also
luminescent, a feature that allows one to track the transformation of 1 to 2 inside such cells …
2′-bipyridine, thp= tris (hydroxymethyl) phosphine] is both strongly luminescent and
photoactive toward carbon monoxide release. It is stable in aerated aqueous media, is
incorporated into cells from the human prostatic carcinoma cell line PPC-1, and shows no
apparent cytotoxicity. Furthermore, the solvated Re (I) photoproduct of CO release (2) is also
luminescent, a feature that allows one to track the transformation of 1 to 2 inside such cells …
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