A new stereoselective synthesis of chiral γ-functionalized (E)-allylic amines
G Reginato, A Mordini, F Messina, A Degl'Innocenti… - Tetrahedron, 1996 - Elsevier
Chiral t-Boc protected propargylic amines have been obtained starting from
aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates
affords an easy regio-and stereocontrolled route to the corresponding γ-stannylated (E)-
allylamines which are useful intermediates for the synthesis of the corresponding γ-
funtionalized allylic systems.
aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates
affords an easy regio-and stereocontrolled route to the corresponding γ-stannylated (E)-
allylamines which are useful intermediates for the synthesis of the corresponding γ-
funtionalized allylic systems.
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