Absolute stereochemistries of the aplysiatoxins and oscillatoxin A
RE Moore, AJ Blackman, CE Cheuk… - The Journal of …, 1984 - ACS Publications
RE Moore, AJ Blackman, CE Cheuk, JS Mynderse, GK Matsumoto, J Clardy, RW Woodard…
The Journal of Organic Chemistry, 1984•ACS PublicationsOptical and proton NMR spectral studies of the aplysiatoxinsand derivatives, degradation
products of the toxins, and an X-ray crystallographic analysis of 19, 21-dibromoaplysiatoxin
show that the absolute configurations of the ten asymmetriccarbons are 3S, 4fi, 7S, 9S, 10S,
llfi, 12S, 15S, 29R, 30fi. The 31-nor compound, oscillatoxin
products of the toxins, and an X-ray crystallographic analysis of 19, 21-dibromoaplysiatoxin
show that the absolute configurations of the ten asymmetriccarbons are 3S, 4fi, 7S, 9S, 10S,
llfi, 12S, 15S, 29R, 30fi. The 31-nor compound, oscillatoxin
Optical and proton NMR spectral studies of the aplysiatoxinsand derivatives, degradation products of the toxins, and an X-ray crystallographic analysis of 19, 21-dibromoaplysiatoxin show that the absolute configurations of the ten asymmetriccarbons are 3S, 4fi, 7S, 9S, 10S, llfi, 12S, 15S, 29R, 30fi. The 31-nor compound, oscillatoxin
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