Accurate LLI and LAMPE Estimation Using the Mechanistic Modeling Approach with Layered Oxides

M Dubarry, V Agrawal, M Hüske… - Journal of The …, 2023 - iopscience.iop.org
Journal of The Electrochemical Society, 2023iopscience.iop.org
In the past decade and half since their introduction, multiple frameworks of mechanistic
models were made available to enable the quantification of loss of lithium inventory and loss
of active materials. They usually come either with capacity/state of charge-or lithiation-based
matching for the electrodes. While both approaches were believed to be equivalent, the
present work will show that they are not when used with materials that are not fully
delithiated at end-of-charge because they differ on how they account for inaccessible …
Abstract
In the past decade and half since their introduction, multiple frameworks of mechanistic models were made available to enable the quantification of loss of lithium inventory and loss of active materials. They usually come either with capacity/state of charge-or lithiation-based matching for the electrodes. While both approaches were believed to be equivalent, the present work will show that they are not when used with materials that are not fully delithiated at end-of-charge because they differ on how they account for inaccessible lithium. Herein, we will explain these discrepancies and propose new equations to improve both types of frameworks.
iopscience.iop.org
以上显示的是最相近的搜索结果。 查看全部搜索结果