Urban air and soil quality has been deteriorating during the past few years due to urbanization, industrialization and increased number of vehicles. The goal of the current study was to assess the Air Pollution Tolerance Index (APTI) and heavy metal absorption (Pb, Cd, Zn, and Ni) potential by ten selected trees planted along the roadside in the metropolitan city of Lahore, Pakistan. APTI was estimated on the basis of biochemical parameters (chlorophyll content, ascorbic acid, pH and relative water contents) of plant extract, while heavy metals (HMs) accumulation potential was measured by a digestion method. The highest APTI was estimated in P. longifolia (78.9), followed by A. scholarils (75.9) and M. indica (71.9). Overall, these three species have significant closeness among the higher pollution-tolerance results. The poor APTI result was determined in F. religiosa (19.5) and E. citriodora (14.9). The highest Pb contents were observed in P. longifolia and M. indica i.e., 135 and 132 mg/kg, respectively. Similarly, the highest Zn contents were found in P. longifolia and S. cumini with 130 and 132 mg/kg, respectively. The Ni concentration was observed highest in P. longifolia (34 mg/kg), but in the remaining species, it is almost the same trend of Ni accumulation. Combining these trees can be useful for fostering green-belt growth along roadsides to reduce air and soil pollution and achieve environmental sustainability. But unfortunately, these species are not planted well across the roadside as they have very little biodiversity index, as compared to other species. These species should be planted in urban areas to enhance biodiversity in the urban ecosystem and make them sustainable cities and communities.