An efficient Sm and Ge co-doped ceria nanocomposite electrolyte for low temperature solid oxide fuel cells

MS Arshad, R Raza, MA Ahmad, G Abbas, A Ali… - Ceramics …, 2018 - Elsevier
MS Arshad, R Raza, MA Ahmad, G Abbas, A Ali, A Rafique, MK Ullah, S Rauf, MI Asghar
Ceramics International, 2018Elsevier
In this study we present a new nanocomposite electrolyte based on samarium (Sm) and
germanium (Ge) co-doped ceria Ce 0.7 Sm 0.15 Ge 0.15 O 2-δ (SGeDC). The
nanocomposite electrolyte was prepared using co-precipitation method. The crystal structure
and surface morphology were determined using x-ray diffraction (XRD) and scanning
electron microscopy (SEM), respectively. Four probe dc conductivity indicated the value of
0.074 S/cm at 650° C. The Fuel cell performance was carried out using hydrogen as fuel …
Abstract
In this study we present a new nanocomposite electrolyte based on samarium (Sm) and germanium (Ge) co-doped ceria Ce0.7Sm0.15Ge0.15O2-δ (SGeDC). The nanocomposite electrolyte was prepared using co-precipitation method. The crystal structure and surface morphology were determined using x-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Four probe dc conductivity indicated the value of 0.074 S/cm at 650 °C. The Fuel cell performance was carried out using hydrogen as fuel. The maximum OCV observed was 0.95 V while the peak power density came out to be 600 mW/cm2 at 600 °C. It is suggested that adding Ge, the conductivity as well as performance of this new nanocomposite electrolyte is comparatively enhanced and it can find potential applications in low temperature solid oxide Fuel cells (LTSOFCs).
Elsevier
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