Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2

JL Peltier, R Jazzar, M Melaimi… - Chemical …, 2016 - pubs.rsc.org
Chemical Communications, 2016pubs.rsc.org
An efficient and selective Cu-catalysed hydrohydrazination of terminal alkynes with parent
hydrazine is reported. The methodology tolerates a broad range of functional groups, allows
for the synthesis of symmetrical and unsymmetrical azines, and can be extended to
hydrazine derivatives and amines.
An efficient and selective Cu-catalysed hydrohydrazination of terminal alkynes with parent hydrazine is reported. The methodology tolerates a broad range of functional groups, allows for the synthesis of symmetrical and unsymmetrical azines, and can be extended to hydrazine derivatives and amines.
The Royal Society of Chemistry
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