In this work, we studied the sintering process of two homogeneous polycyclic aromatic hydrocarbon (PAH) clusters with diameters in the range of 3–6 nm using molecular dynamics (MD) simulations. The sintering process was quantified through monitoring the solvent accessible surface area (SASA) and the distance between the center of mass (COM) of the two PAH clusters. The effect of temperature and crosslinking level of PAH clusters on sintering was investigated. The results show that the sintering rate of two PAH clusters at a certain temperature T is largely dependent on the melting point (T MP) of the PAH cluster. When T is higher than T MP, the characteristic sintering time (τ s) is around 10− 2 ns and sintering is not affected by the crosslinking level as the PAH clusters are liquid-like. In contrast, when T is much lower than T MP, the PAH clusters sinter rather slowly with τ s> 5 ns, and the sintering process is hindered by the crosslinks between PAH molecules within solid-like PAH clusters due to the enhanced steric effect.