Benzene dimer: a polar molecule

KC Janda, JC Hemminger, JS Winn… - The Journal of …, 1975 - pubs.aip.org
… Almost all studies of the orientational dependence of benzene … electric deflection of molecular
beams of benzene dimer. The … that the dimer of benzene has an electric dipole moment. …

[PDF][PDF] Structure of the Benzene Dimer-Governed by Dynamics.

M Schnell, U Erlekam, PR Bunker… - Angewandte …, 2013 - cloud.fhi-berlin.mpg.de
… beam[2] determined that it is polar, which suggests that its … surface has been developed
for the benzene dimer.[1, 6] … The three tunneling motions of the benzene dimer that play the …

A quantum chemistry study of benzene dimer

RL Jaffe, GD Smith - The Journal of chemical physics, 1996 - pubs.aip.org
… (MPI) to detect benzene dimers. They also concluded that the benzene molecules are
interchangeable, and suggested that a polar V-shaped dimer geometry with C2v symmetry is …

Floppy structure of the benzene dimer: Ab initio calculation on the structure and dipole moment

P Hobza, HL Selzle, EW Schlag - The Journal of chemical physics, 1990 - pubs.aip.org
… The dimer has been observedl to be polarbenzene dimer; therefore we cannot neglect a
priori the correlation correction to this term. The potential enefgy surface of the benzene dimer

Aromatic-aromatic interactions: free energy profiles for the benzene dimer in water, chloroform, and liquid benzene

WL Jorgensen, DL Severance - Journal of the American Chemical …, 1990 - ACS Publications
… of pure liquid benzene, benzene in dilute aqueous solution, and the benzene dimer in
water … for the association of the benzene dimer in liquid benzene, water, andchloroform that …

Molecular beam studies of benzene dimer, hexafluorobenzene dimer, and benzene–hexafluorobenzene

JM Steed, TA Dixon, W Klemperer - The Journal of Chemical Physics, 1979 - pubs.aip.org
… While all three species (CSHS)2, (CsFs)2, CsHs-CsFs are polar, it is clear that the polarity
of these dimers is due to charge redistribution associated with forming the weak bond, in an …

Benzene dimer: A good model for π− π interactions in proteins? A comparison between the benzene and the toluene dimers in the gas phase and in an aqueous …

C Chipot, R Jaffe, B Maigret, DA Pearlman… - Journal of the …, 1996 - ACS Publications
… (QM) or molecular mechanical (MM) calculations on the archetypical benzene dimer to account
… that the ZPE for the toluene dimer should be close enough to that of the benzene dimer. …

The rotational spectrum, structure and dynamics of a benzene dimer

E Arunan, HS Gutowsky - The Journal of chemical physics, 1993 - pubs.aip.org
… The benzene-benzene interaction is typical of aromatic systems. As such it has been an …
Early molecular beam observations3 ,4 showed the dimer to be polar, and "coarsely identified" …

Dimers of aromatic molecules: (Benzene)2, (toluene)2, and benzene–toluene

K Law, M Schauer, ER Bernstein - The Journal of chemical physics, 1984 - pubs.aip.org
… (hexafluorobenzene-benzene) dimer the two molecules are … technique selects for polar
molecules and clusters only and … tations of benzene molecules in the benzene dimer have ap…

Structure and vibrational dynamics of the benzene dimer

V Špirko, O Engkvist, P Soldán, HL Selzle… - The Journal of …, 1999 - pubs.aip.org
… The HF/cc-pVDZ’ multipole expansion and local polarizabilities for the benzene molecule
are presented in Table I. The scaling parameter C for the dispersion energy equation 1 was …