Bis (imino) phenoxide complexes of zirconium: synthesis, structural characterization and solvent-free ring-opening polymerization of cyclic esters and lactides
Dalton Transactions, 2010•pubs.rsc.org
Bis (imino) phenoxide complexes of zirconium possess spectacular reactivity towards the
solvent-free polymerization of cyclic ester monomers and lactides. Polymerization of lactide
is living and the resulting product has exceptionally high number average molecular weights
(Mn). Polymerization of β-butyrolactone gives syndiotactic poly (3-hydroxybutyrate) with
good Mn and molecular weight distribution (MWD).
solvent-free polymerization of cyclic ester monomers and lactides. Polymerization of lactide
is living and the resulting product has exceptionally high number average molecular weights
(Mn). Polymerization of β-butyrolactone gives syndiotactic poly (3-hydroxybutyrate) with
good Mn and molecular weight distribution (MWD).
Bis(imino)phenoxide complexes of zirconium possess spectacular reactivity towards the solvent-free polymerization of cyclic ester monomers and lactides. Polymerization of lactide is living and the resulting product has exceptionally high number average molecular weights (Mn). Polymerization of β-butyrolactone gives syndiotactic poly(3-hydroxybutyrate) with good Mn and molecular weight distribution (MWD).
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