… nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky
thiolate ligands, along with halides, as the surface capping agent promotes the formation of …

… bulky NHC-1 ligands that lead to a rather open metal surface … 3 exhibit no reactivity, which
may be due to its nearly full … promoting effect of surface ligands on catalysis by metal nano- …

… of AgNMs with different ligands, S-Adm and MSA, following … -surface reactivities towards
exchange reactions with diverse … probe the free-radical generation promoted by AgNCs in cells, …

… the 3methoxythiophenol ligand is replaced with a bulkier ligand like … We also tried the ion
exchange reactions in toluene and tri… and revealing what promotes the size transformation from …

… Compared to Ag146, the [Ag141X12(S- Adm)40]3+ (X = Cl, Br… that can promote the
transformation reactions. Recently, the … Ag141 structure has bulky and very rigid adamantyl …

… synthesis and crystal structure of [Pd1Ag28(S-Adm)18(PPh3)4]2+ (… In addition, we explored
the reactivity of Pd1Ag28 … 3.3 μs, which will promote the application of Pd1Ag28 nanocluster …

… kernels show high chemical and physical activities [17, 18], … is very significant to promote the
development of nanocluster … Å, which is close to that of the bulk Ag [74], indicating the strong …

… and as a mild reducing agent to promote the reduction of Ag+, … − ligands for regioselective
distribution on the surface of the … Assembly of the thiolated [Au1Ag22(S-Adm)12]3+ superatom …

… This may enhance fast light absorption and efficient … e–f) showed that the majority of AgBr
NPs are deposited on the surface … for subsequent reactions with no perceptible efficiency loss. …

… Surface ligands play important roles in controlling the size and shape of metal nanoparticles
… their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, …