Catalysis of Kumada–Tamao–Corriu coupling by a (POCOP) Rh pincer complex
SD Timpa, CM Fafard, DE Herbert, OV Ozerov - Dalton Transactions, 2011 - pubs.rsc.org
SD Timpa, CM Fafard, DE Herbert, OV Ozerov
Dalton Transactions, 2011•pubs.rsc.orgA pincer-based (POCOP) Rh catalyst is demonstrated to be an active and well-defined
catalyst for the coupling of select aryl and alkyl Grignards with aryl iodides. The proposed
intermediacy of oxidative addition of aryl halides to (POCOP) RhI is supported by the
isolation of the oxidative addition product.
catalyst for the coupling of select aryl and alkyl Grignards with aryl iodides. The proposed
intermediacy of oxidative addition of aryl halides to (POCOP) RhI is supported by the
isolation of the oxidative addition product.
A pincer-based (POCOP)Rh catalyst is demonstrated to be an active and well-defined catalyst for the coupling of select aryl and alkyl Grignards with aryl iodides. The proposed intermediacy of oxidative addition of aryl halides to (POCOP)RhI is supported by the isolation of the oxidative addition product.
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