… to introduce axial chirality into metal terpyridine complexes, … terpyridines close a macrocycle
which has been preorganized (templated) by the formation of the metal-terpyridine complex…

… -base macrocycles and less rigid polyamine-macrocycles in which the rigidity of terpyridine
is … spectroscopic properties of transition metal complexes with these ligands are presented …

… Meanwhile, unlike {M(bpy) 3 } which can be chiral complexes (formation of fac and mer …
-assembling of the ditopic terpyridine ligand and Cd 2+ , a mixture of macrocycles was achieved. …

… ] n+ complexes in which two almost planar terpyridine molecules are nearly … chiral [M(L–L)
3 ] n+ species, the [M(terpy) 2 ] n+ motif is achiral. Accordingly, coordination of two terpyridine …

… chiral groups and the terpyridine is larger. CD spectroscopy of the corresponding ruthenium(II)
complex in an apolar solvent (dodecane) revealed chirality in the … (b), the macrocycle was …

… expanded in the future with chiral terpyridine ligands, for which … Chiral and achiral macrocyclic
metallo-assemblies have … quantitative formation of bis-terpyridine complexes. In the case …

… complexes of the directionalized terpyridine mimic, pyridyl-phenanthroline, 21 are chiral
and … the basis for the absence of figure-eight macrocycle formation with the Fe(II) templates. …

… a series of chiral pincer metal complexes and investigated … reveal that the chirality is transferred
from chiral carbon centers to … the chiral induction efficiency of the [Zn 4 L 4 ] macrocycle is …

… terpyridines in low yields along with the formation of complex mixtures of oligopyridines and
… expected terpyridine 2 in 35% yield, but also the [2 + 6]-cycloaddition product, namely chiral …

… complexes, chirality was introduced by fusing a chiral pinene-cycle in 5,6-position in the
terpyridine ring, thus making the ligand itself chiral… macrocyclic complexes derived from a chiral …