Chromium (III) removal by weak acid exchanger Amberlite IRC-50 (Na)

S Mustafa, KH Shah, A Naeem, M Waseem… - Journal of Hazardous …, 2008 - Elsevier
Journal of Hazardous Materials, 2008Elsevier
Chromium (III) sorption on a weakly macroporous cation exchanger Amberlite IRC-50 (Na) is
studied as a function of time and temperature. The rate constant values for chromium (III)
sorption are calculated both for film and particle diffusion processes. The temperature is
found to have a positive effect on both the diffusional processes. The high values of energy
of activation confirm the particle diffusional nature of the process. The pH changes in the
system show a competition between the Cr (OH) 2+ and H+ ions for the exchange sites of …
Chromium (III) sorption on a weakly macroporous cation exchanger Amberlite IRC-50 (Na) is studied as a function of time and temperature. The rate constant values for chromium (III) sorption are calculated both for film and particle diffusion processes. The temperature is found to have a positive effect on both the diffusional processes. The high values of energy of activation confirm the particle diffusional nature of the process. The pH changes in the system show a competition between the Cr(OH)2+ and H+ ions for the exchange sites of the adsorbent. Equilibrium data are explained with the help of Langmuir equation. Various thermodynamic parameters (ΔH°, ΔS° and ΔG°) from chromium (III) exchange on the resin are calculated.
Elsevier
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