Coke formation during the hydrotreatment of bio-oil using NiMo and CoMo catalysts

S Kadarwati, X Hu, R Gunawan, R Westerhof… - Fuel processing …, 2017 - Elsevier
… It is important to understand how the sugars in bio-oil contribute to the coke formation. … of
the NiMo and CoMo catalysts on the coke formation during the hydrotreatment of bio-oil under …

Bio-oil hydrotreating over conventional CoMo & NiMo catalysts: The role of reaction conditions and additives

J Horáček, D Kubička - Fuel, 2017 - Elsevier
… by coke formed from the unstable bio-oil, and catalyst decomposition into dust. Catalyst
decomposition was observed in catalyst … 20 and 100% of length from the top of the catalyst layer. …

Effects of temperature on the hydrotreatment behaviour of pyrolysis bio-oil and coke formation in a continuous hydrotreatment reactor

M Gholizadeh, R Gunawan, X Hu… - Fuel Processing …, 2016 - Elsevier
bio-oil into a liquid fuel that can be used in the existing vehicles. … NiMo/γ-Al 2 O 3 and/or
CoMo/γ-Al 2 O 3 were used as … before the bio-oil came into contact with the NiMo catalyst. …

Characterization of deactivated bio-oil hydrotreating catalysts

H Wang, Y Wang - Topics in catalysis, 2016 - Springer
… as the first-step catalyst and a sulfided CoMo or NiMo on a carbon catalyst in a two-step …
that coke formation is the major issue that causes deactivation of bio-oil hydrotreating catalysts. …

Advances and perspectives of bio-oil hydrotreatment for biofuel production

M Gholizadeh, S Zhang, X Hu, Y Wang - Energy & Fuels, 2023 - ACS Publications
… Deactivation of the catalyst by the coke formed through the polymerization of the lignin … over
sulfided NiMo and CoMo catalysts. 75–90 g of each catalyst or their mixture (50 g of NiMo in …

Effective suppression of coke formation with lignin-derived oil during the upgrading of pyrolysis oils

DC Lv, K Jiang, K Li, YQ Liu, D Wang, YY Ye - Biomass and Bioenergy, 2022 - Elsevier
… In this study, hydrotreatment of pine pyrolysis oils with NiMo/γ-Al 2 O 3 … of the NiMo catalyst
by eliminating more oxygenated compounds, the HDO of bio-oil catalyzed by NiMo, which …

Advances and challenges in the valorization of bio-oil: hydrodeoxygenation using carbon-supported catalysts

T Cordero-Lanzac, J Rodriguez-Mirasol… - Energy & …, 2021 - ACS Publications
… of different model compounds over a NiMo catalyst, which was, from … tendency to coke
formation and decreases catalyst stability. … VGO with 10% hydrotreated bio-oil, assuming 2000 dry …

Hydrodeoxygenation and hydrocracking of solvolysed lignocellulosic biomass by oxide, reduced and sulphide form of NiMo, Ni, Mo and Pd catalysts

M Grilc, B Likozar, J Levec - Applied Catalysis B: Environmental, 2014 - Elsevier
… by hydrotreatment utilizing heterogeneous catalysis at 300 C … The kinetic studies of real
bio-oil HDO are rare and always … results in the formation of the coke during hydrotreatment [11] …

Hydrotreatment of pyrolysis bio-oil: A review

Y Han, M Gholizadeh, CC Tran, S Kaliaguine… - Fuel processing …, 2019 - Elsevier
… a single-stage NiMo/Al 2 O 3 or CoMo/Al 2 O 3 is inappropriate for HDO due to quick and
severe coke formation [11]. First reported by Gagnon and Kaliaguine [12], Ru catalyst had been …

Production of renewable diesel through the hydroprocessing of lignocellulosic biomass-derived bio-oil: A review

M Patel, A Kumar - Renewable and Sustainable Energy Reviews, 2016 - Elsevier
… of upgrading bio-oil because there are hydrotreating units in place … Coke formation at the
time of the reaction is the main … the traditional sulfide NiMo/CoMo catalyst supported on gamma …