Correlations for diffusion constants

AM Brown, MF Ashby - Acta Metallurgica, 1980 - Elsevier
… useful correlations for the material constants which describe lattice diffusion and grain
boundary diffusion in metals and ceramics. All three correlations must be regarded as empirical (…

[PDF][PDF] Correlation of diffusion coefficients in dilute solutions

CR Wilke, P Chang - AIChE journal, 1955 - dns2.asia.edu.tw
… The diffusion coefficient is normally defined and assumed in this study to be the
proportionality constant in the rate equation written for undirectional mass transfer as follows : …

Rate constants for reactions in viscous media: correlation between the viscosity of the solvent and the rate constant of the diffusion-controlled reactions

AF Olea, JK Thomas - Journal of the American Chemical Society, 1988 - ACS Publications
… does predict rate constants that are in … diffusion constant for the reactants in the media
studied. A free volume theory with transition-state concepts suggests that the diffusion constants of …

Understanding the linear correlation between diffusion coefficient and molecular weight. A model to estimate diffusion coefficients in acetonitrile solutions

DP Valencia, FJ González - Electrochemistry Communications, 2011 - Elsevier
… fact that they involve constants which cannot be easily … diffusion coefficients. Another way
to address the problem consists in the use of single empirical linear plots between the diffusion

Estimation of diffusion coefficients by using a linear correlation between the diffusion coefficient and molecular weight

DP Valencia, FJ González - Journal of Electroanalytical Chemistry, 2012 - Elsevier
… At our knowledge, experimental determinations of Sutherland constant are not available,
because generally, this constant is stated to be either 4 or 6 depending on an intuitive criterion …

[PDF][PDF] A linear free energy relationship for gas‐solid interactions: correlation between surface rate constant and diffusion coefficient of oxygen tracer exchange for …

R Merkle, J Maier, HJM Bouwmeester - … Chemie International Edition, 2004 - ris.utwente.nl
correlations hold only for families of materials with similar mechanistic parameters. A detailed
treatment of effective rate constants … the microscopic rate constant of the rate determining …

Correlation and prediction of diffusion coefficients by use of a generalized corresponding states principle

AS Teja - Industrial & engineering chemistry fundamentals, 1985 - ACS Publications
… satisfactory theory exists for diffusion in liquids and dense … to develop correlations which
relate the diffusion coefficient to other … to the correlation and prediction of diffusion coefficients in …

Measurement and correlation of binary diffusion coefficients in near critical fluids

OJ Catchpole, MB King - Industrial & Engineering Chemistry …, 1994 - ACS Publications
… is the working correlation for predicting the self diffusion coefficient in eq 9. The constant C
was … in the section on correlation of binary diffusion coefficients. Methods for predicting the self …

Measurement and correlation of diffusion coefficients for CO2 and rich-gas applications

TA Renner - SPE reservoir engineering, 1988 - onepetro.org
… The experimental diffusion coefficients obtained from this study have also been correlated, …
where a and b are specific constants for each particular diffusing substance and µ j is the …

Normal mode analysis of liquid CS2: Velocity correlation functions and self‐diffusion constants

P Moore, T Keyes - The Journal of chemical physics, 1994 - pubs.aip.org
… We show that time correlation functions and the various self-diffusion con… correlations,
trans-J.. velocity correlations, rotational velocity correlations, and corresponding diffusion constants