Low Pressure Cold Spray (LPCS) was used to produce Al based powder coatings on X80 low carbon steel, AA2024 Al alloy and AZ31 Magnesium alloy substrates. The corrosion protection provided by these coatings was evaluated by electrochemical measurements (polarization curves, electrochemical impedance spectroscopy) in 1M NaCl electrolyte. The microstructures and electrochemical behavior of the Al based coatings were investigated comparing with pure Al. Electrochemical measurements showed that cold sprayed Al-Al2O3 coatings exhibit:(i) corrosion potential of the Al coating is similar to solid Al,(ii) corrosion potential of the Al-Al2O3 coatings is comparable as Al, and (iii) change of polarization processes occurs for Al-Al2O3 coatings. The immersion tests revealed dependence of corrosion resistance on Al2O3 content. The electrochemical corrosion mechanisms of the coatings and microstructure were discussed. The coatings show a typical layered cold sprayed material structure.