Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups.
MV Sheridan, K Lam… - Angewandte Chemie …, 2013 - search.ebscohost.com
MV Sheridan, K Lam, WE Geiger
Angewandte Chemie International Edition, 2013•search.ebscohost.comOne with the surface: A method is presented for electrode modification with terminal alkynes
and alkenes. Direct oxidation of these moieties leads to efficient grafting onto glassy carbon,
gold, platinum, and indium tin oxide surfaces. Various ferrocenes and 5, 10, 15, 20‐(4‐
ethynylphenyl) porphyrin were attached in this way.
and alkenes. Direct oxidation of these moieties leads to efficient grafting onto glassy carbon,
gold, platinum, and indium tin oxide surfaces. Various ferrocenes and 5, 10, 15, 20‐(4‐
ethynylphenyl) porphyrin were attached in this way.
Abstract
One with the surface: A method is presented for electrode modification with terminal alkynes and alkenes. Direct oxidation of these moieties leads to efficient grafting onto glassy carbon, gold, platinum, and indium tin oxide surfaces. Various ferrocenes and 5, 10, 15, 20‐(4‐ethynylphenyl) porphyrin were attached in this way.
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