Design and UV-curable behaviour of boron based reactive diluent for epoxy acrylate oligomer used for flame retardant wood coating

SU Chambhare, GP Lokhande… - Designed Monomers and …, 2017 - Taylor & Francis
SU Chambhare, GP Lokhande, RN Jagtap
Designed Monomers and Polymers, 2017Taylor & Francis
Difunctional boron-containing reactive flame retardant for UV-curable epoxy acrylate
oligomer was synthesized from phenyl boronic acid and glycidyl methacrylate. The
synthesized reactive diluent was utilized to formulate ultraviolet (UV)-curable wood coatings.
The weight fractions of reactive diluent in coatings formulation was varied from 5 to 25 wt%
with constant photoinitiator concentration. The molecular structure of reactive flame retardant
was confirmed by Fourier-transform infrared, Nuclear magnetic resonance (NMR) and 11B …
Abstract
Difunctional boron-containing reactive flame retardant for UV-curable epoxy acrylate oligomer was synthesized from phenyl boronic acid and glycidyl methacrylate. The synthesized reactive diluent was utilized to formulate ultraviolet (UV)-curable wood coatings. The weight fractions of reactive diluent in coatings formulation was varied from 5 to 25 wt % with constant photoinitiator concentration. The molecular structure of reactive flame retardant was confirmed by Fourier-transform infrared, Nuclear magnetic resonance (NMR) and 11B NMR spectral analysis. Further, the efficacy of flame retardant behaviour of coatings was evaluated using limiting oxygen index and UL-94 vertical burning test. Thermal stability of cured coatings films were estimated from thermogravimetric and differential scanning calorimetry analysis. The effects of varying concentration of reactive diluent on the viscosity of coatings formulation along with optical, mechanical and chemical resistance properties of coatings were also evaluated. The coatings gel content, water absorption behaviour, contact angle analysis and stain resistance were also studied.
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