Desmotropy, Polymorphism, and Solid‐State Proton Transfer: Four Solid Forms of an Aromatic o‐Hydroxy Schiff Base
The Schiff base derived from salicylaldehyde and 2‐amino‐3‐hydroxypyridine affords a
diversity of solid forms, two polymorphic pairs of the enol‐imino (D1 a and D1 b) and keto‐
amino (D2 a and D2 b) desmotropes. The isolated phases, identified by IR spectroscopy, X‐
ray crystallography, and 13C cross‐polarization/magnetic angle spinning (CP/MAS) NMR
spectroscopy, display essentially planar molecular conformations characterized by strong
intramolecular hydrogen bonds of the O H⋅⋅⋅ N (D1) or N H⋅⋅⋅ O (D2) type. A change …
diversity of solid forms, two polymorphic pairs of the enol‐imino (D1 a and D1 b) and keto‐
amino (D2 a and D2 b) desmotropes. The isolated phases, identified by IR spectroscopy, X‐
ray crystallography, and 13C cross‐polarization/magnetic angle spinning (CP/MAS) NMR
spectroscopy, display essentially planar molecular conformations characterized by strong
intramolecular hydrogen bonds of the O H⋅⋅⋅ N (D1) or N H⋅⋅⋅ O (D2) type. A change …
Desmotropy, polymorphism and solid-state proton transfer: four solid forms of an aromatic o-hydroxy Schiff base
I Đilović, M Rubčić, K Užarević, I Halasz… - Past, Present and Future …, 2013 - croris.hr
… Desmotropy, polymorphism and solid-state proton transfer: four solid forms of an aromatic
o-hydroxy Schiff base (CROSBI ID 607014) … Desmotropy, polymorphism and solid-state
proton transfer: four solid forms of an aromatic o-hydroxy Schiff base // Past, Present and
Future of Crystallography@ Politecnico di Milano: From Small Molecules to Macromolecules
and Supramolecular Structures / Metrangolo, Pierangelo ; Resnati, Giuseppe ; Cavallo,
Gabriella et al. (ur.). Milano: Politecnico di Milano, 2013. … Desmotropy, polymorphism …
o-hydroxy Schiff base (CROSBI ID 607014) … Desmotropy, polymorphism and solid-state
proton transfer: four solid forms of an aromatic o-hydroxy Schiff base // Past, Present and
Future of Crystallography@ Politecnico di Milano: From Small Molecules to Macromolecules
and Supramolecular Structures / Metrangolo, Pierangelo ; Resnati, Giuseppe ; Cavallo,
Gabriella et al. (ur.). Milano: Politecnico di Milano, 2013. … Desmotropy, polymorphism …