Effect of boron and phosphate compounds on physical, mechanical, and fire properties of wood–polypropylene composites

N Ayrilmis, T Akbulut, T Dundar, RH White… - … and Building Materials, 2012 - Elsevier
Construction and Building Materials, 2012Elsevier
Physical, mechanical, and fire properties of the injection-molded wood flour/polypropylene
composites incorporated with different contents of boron compounds; borax/boric acid and
zinc borate, and phosphate compounds; mono and diammonium phosphates were
investigated. The effect of the coupling agent content, maleic anhydride-grafted
polypropylene, on the properties of the composites with fire-retardant was also investigated.
The composites with the zinc borate had the highest dimensional stability and strength in the …
Physical, mechanical, and fire properties of the injection-molded wood flour/polypropylene composites incorporated with different contents of boron compounds; borax/boric acid and zinc borate, and phosphate compounds; mono and diammonium phosphates were investigated. The effect of the coupling agent content, maleic anhydride-grafted polypropylene, on the properties of the composites with fire-retardant was also investigated. The composites with the zinc borate had the highest dimensional stability and strength in the bending, tensile, and izod impact, followed by the monoammonium phosphate, borax/boric acid, and diammonium phosphate treatments. The treatments produced modest improvements in fire performance as indicated by reductions in the heat release rates. Best results were achieved with the phosphate treatments. The Scanning Electron Microscope–Energy Dispersive Spectroscopy elemental mapping of the samples revealed that the outer surface of the wood fibers was coated by some crystalline deposits of the fire-retardants.
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