Effects of lanthanum modification on dielectric properties of Pb(Zr0.90,Ti0.10)O3 ceramics: enhanced antiferroelectric stability

A Peláiz-Barranco, JDS Guerra… - Journal of materials …, 2008 - Springer
Journal of materials science, 2008Springer
Lanthanum modified lead zirconate titanate ceramics with lanthanum content changing from
2 to 6 at% La and a Zr/Ti ratio of 90/10 (PLZT x/90/10) have been analyzed by using X-ray
diffraction, dielectric response, differential scanning calorimetry, and ferroelectric hysteresis.
An antiferroelectric state was found to be stabilized, whereas the long-range ferroelectric
state was disrupted by lanthanum substitution on the lead sites. A ferroelectric state is shown
to be stable over an antiferroelectric state for low lanthanum contents in a wide temperature …
Abstract
Lanthanum modified lead zirconate titanate ceramics with lanthanum content changing from 2 to 6 at% La and a Zr/Ti ratio of 90/10 (PLZT x/90/10) have been analyzed by using X-ray diffraction, dielectric response, differential scanning calorimetry, and ferroelectric hysteresis. An antiferroelectric state was found to be stabilized, whereas the long-range ferroelectric state was disrupted by lanthanum substitution on the lead sites. A ferroelectric state is shown to be stable over an antiferroelectric state for low lanthanum contents in a wide temperature range, where both phases coexist. With the increase of the lanthanum concentration, the long-range coherency of the ferroelectric state is suppressed, i.e., the temperature range of the ferroelectric state stability decreased, disappearing for > 3 at% La.
Springer
以上显示的是最相近的搜索结果。 查看全部搜索结果