Effects of reaction temperature and inlet oxidizing gas flow rate on IG-110 graphite oxidation used in HTR-PM

X Sun, Y Dong, Y Zhou, Z Li, L Shi, Y Sun… - Journal of Nuclear …, 2017 - Taylor & Francis
X Sun, Y Dong, Y Zhou, Z Li, L Shi, Y Sun, Z Zhang
Journal of Nuclear Science and Technology, 2017Taylor & Francis
The oxidation behavior of a selected nuclear graphite (IG-110) used in Pebble-bed Module
High Temperature gas-cooled Reactor was investigated under the condition of air ingress
accident. The oblate rectangular specimen was oxidized by oxidant gas with oxygen mole
fraction of 20% and flow rates of 125–500 ml/min at temperature of 400–1200° C.
Experiment results indicate that the oxidation behavior can also be classified into three
regimes according to temperature. The regime I at 400–550° C has lower apparent …
Abstract
The oxidation behavior of a selected nuclear graphite (IG-110) used in Pebble-bed Module High Temperature gas-cooled Reactor was investigated under the condition of air ingress accident. The oblate rectangular specimen was oxidized by oxidant gas with oxygen mole fraction of 20% and flow rates of 125–500 ml/min at temperature of 400–1200 °C. Experiment results indicate that the oxidation behavior can also be classified into three regimes according to temperature. The regime I at 400–550 °C has lower apparent activation energies of 75.57–138.59 kJ/mol when the gas flow rate is 125–500 ml/min. In the regime II at 600–900 °C, the oxidation rate restricted by the oxygen supply to graphite is almost stable with the increase of temperature. In the regime III above 900 °C, the oxidation rate increases obviously with the increase of temperature. With the increase of inlet gas flow from 125 to 500 ml/min, the apparent activation energy in regime I is increased and the stableness of oxidation rate in regime II is reduced.
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