Efficient Synthesis of Tris(acetonitrile)‐(η5‐cyclopentadienyl)‐ ruthenium(II) Hexafluorophosphate via Ruthenocene
EP Kündig, FR Monnier - Advanced Synthesis & Catalysis, 2004 - Wiley Online Library
Advanced Synthesis & Catalysis, 2004•Wiley Online Library
Abstract [Ru (η5‐C5H5)(CH3CN) 3][PF6](1), a versatile precursor to catalysts containing the
CpRu+ complex fragment, can be obtained in high yield via Cp/naphthalene exchange in
ruthenocene. This new route via the complex [RuCp (naphthalene)][PF6](4) avoids both
highly toxic thallium reagents and the need for a photoreactor.
CpRu+ complex fragment, can be obtained in high yield via Cp/naphthalene exchange in
ruthenocene. This new route via the complex [RuCp (naphthalene)][PF6](4) avoids both
highly toxic thallium reagents and the need for a photoreactor.
Abstract
[Ru(η5‐C5H5)(CH3CN)3][PF6] (1), a versatile precursor to catalysts containing the CpRu+ complex fragment, can be obtained in high yield via Cp/naphthalene exchange in ruthenocene. This new route via the complex [RuCp(naphthalene)][PF6] (4) avoids both highly toxic thallium reagents and the need for a photoreactor.
Wiley Online Library以上显示的是最相近的搜索结果。 查看全部搜索结果