Electron and hole transport in an anthracene-based conjugated polymer

N Camaioni, F Tinti, A Degli Esposti, S Righi… - Applied Physics …, 2012 - pubs.aip.org
The bulk transport properties of an anthracene-containing poly (p-phenylene-ethynylene)-alt-
poly (p-phenylene-vinylene)(AnE-PVstat) were investigated by small-signal time-of-flight.
AnE-PVstat exhibited a very good ambipolar behaviour, consistent with the high
delocalization of both frontier molecular orbitals. The transport of negative carriers was
found to be even faster than that of positive carriers, with an electron drift mobility of about
six times higher than that evaluated for holes, suggesting that conjugated polymers with …
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